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The second law of thermodynamics is a physical law based on universal empirical observation concerning heat and energy interconversions. A simple statement of the law is that heat always flows spontaneously from hotter to colder regions of matter (or 'downhill' in terms of the temperature gradient).
The convection–diffusion equation can be derived in a straightforward way [4] from the continuity equation, which states that the rate of change for a scalar quantity in a differential control volume is given by flow and diffusion into and out of that part of the system along with any generation or consumption inside the control volume: + =, where j is the total flux and R is a net ...
The convection–diffusion equation describes the flow of heat, particles, or other physical quantities in situations where there is both diffusion and convection or advection. For information about the equation, its derivation, and its conceptual importance and consequences, see the main article convection–diffusion equation. This article ...
Fick's first law relates the diffusive flux to the gradient of the concentration. It postulates that the flux goes from regions of high concentration to regions of low concentration, with a magnitude that is proportional to the concentration gradient (spatial derivative), or in simplistic terms the concept that a solute will move from a region of high concentration to a region of low ...
Convection is the heat transfer by the macroscopic movement of a fluid. This type of transfer takes place in a forced-air furnace and in weather systems, for example. Heat transfer by radiation occurs when microwaves, infrared radiation, visible light, or another form of electromagnetic radiation is emitted or absorbed. An obvious example is ...
A prime example of this irreversibility is the transfer of heat by conduction or radiation. It was known long before the discovery of the notion of entropy that when two bodies, initially of different temperatures, come into direct thermal connection, then heat immediately and spontaneously flows from the hotter body to the colder one.
Forced convection: when a fluid is forced to flow over the surface by an internal source such as fans, by stirring, and pumps, creating an artificially induced convection current. [ 3 ] In many real-life applications (e.g. heat losses at solar central receivers or cooling of photovoltaic panels), natural and forced convection occur at the same ...
Convection, especially Rayleigh–Bénard convection, where the convecting fluid is contained by two rigid horizontal plates, is a convenient example of a pattern-forming system. When heat is fed into the system from one direction (usually below), at small values it merely diffuses ( conducts ) from below upward, without causing fluid flow.