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Phenacyl bromide is the organic compound with the formula C 6 H 5 C(O)CH 2 Br. This colourless solid is a powerful lachrymator as well as a useful precursor to other organic compounds. It is prepared by bromination of acetophenone: [2] C 6 H 5 C(O)CH 3 + Br 2 → C 6 H 5 C(O)CH 2 Br + HBr. The compound was first reported in 1871. [3]
A molecule containing a phenacyl group has the formula RCH 2 (CO)C 6 H 5 and the structure shown to the right. Here, R denotes the remainder of the molecule; for instance, if R is Br, then the compound could be called "phenacyl bromide". Note however that in the standard IUPAC nomenclature this compound would instead be called "2-bromo-1 ...
Bromobenzene is an aryl bromide and the simplest of the bromobenzenes, consisting of a benzene ring substituted with one bromine atom. Its chemical formula is C 6 H 5 Br. It is a colourless liquid although older samples can appear yellow. It is a reagent in organic synthesis.
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Some chloroacetyl chloride is also used to produce phenacyl chloride, another chemical intermediate, also used as a tear gas. [3] Phenacyl chloride is synthesized in a Friedel-Crafts acylation of benzene, with an aluminium chloride catalyst: [6] With anisole, it is used for the synthesis of venlafaxine.
F 3 NO: nitrogen trifluoride oxide: 13847-65-9 F 3 NO 2 S: difluoroaminosulfonyl fluoride: 13709-30-3 F 3 NO 3 S: difluoraminooxysulfonyl fluoride: 6816-12-2 F 3 NS: thiazyl trifluoride: 15930-75-3 F 3 NaSn: sodium trifluorostannate: 13782-22-4 F 3 Nd: neodymium trifluoride: 13709-42-7 F 3 OP: phosphoryl fluoride: 13478-20-1 F 3 OTa: tantalum ...
The preferred conditions are the portionwise addition of NBS to a solution of the alkene in 50% aqueous DMSO, DME, THF, or tert-butanol at 0 °C. [3] Formation of a bromonium ion and immediate attack by water gives strong Markovnikov addition and anti stereochemical selectivities.
Phenylacetone, also known as phenyl-2-propanone, is an organic compound with the chemical formula C 6 H 5 CH 2 COCH 3.It is a colorless oil that is soluble in organic solvents.It is a mono-substituted benzene derivative, consisting of an acetone attached to a phenyl group.