Search results
Results from the WOW.Com Content Network
CH 3 (CH 2) 7 CH=CH(CH 2) 11 CO 2 H + O 3 + 0.5 O 2 → CH 3 (CH 2) 7 CO 2 H + HO 2 C(CH 2) 11 CO 2 H. A number of drugs and their intermediates have been produced by ozonolysis. [22] The use of ozone in the pharmaceutical industry is difficult to discern owing to confidentiality considerations. [5]
Methylpentene is an alkene with a molecular formula C 6 H 12.The prefix "methyl-" is derived from the fact that there is a methyl(CH 3) branch, the word root "-pent-" is derived from the fact that there are 5 carbon atoms in the parent chain, while the "-ene" suffix denotes that there is a double bond present, as per IUPAC nomenclature. [1]
As of 2010s, the only commercial manufacturer of 1-pentene was Sasol Ltd., where it is separated from crude by the Fischer-Tropsch process. [2] 2-Pentene has two geometric isomers: cis-2-pentene and trans-2-pentene. Cis-2-Pentene is used in olefin metathesis.
ch 2 =ch 2 + ch 3 ch=chch 3 → 2 ch 2 =chch 3 Transition metal catalyzed hydrovinylation is another important alkene synthesis process starting from alkene itself. [ 31 ] It involves the addition of a hydrogen and a vinyl group (or an alkenyl group) across a double bond.
But by tweaking this structure to a PR 3 Ta(CHt−bu)(Ot−bu) 2 Cl (replacing chloride by t-butoxide and a cyclopentadienyl by an organophosphine, metathesis was established with cis-2-pentene. [45] In another development, certain tungsten oxo complexes of the type W(O)(CHt−Bu)(Cl) 2 (PEt) 3 were also found to be effective. [46]
The oxime first reacts with the ozone to form the corresponding carbonyl oxide, undergoes 1,3-dipolar cycloaddition with the carbonyl reactant to form the cyclic ozonide, as usual for the Criegee intermediate in the ozonolysis of alkenes. If no carbonyl compound is used, the carbonyl oxide may dimerize and form 1,2,4,5-tetraoxanes.
The Chugaev elimination is a chemical reaction that involves the elimination of water from alcohols to produce alkenes.The intermediate is a xanthate.It is named for its discoverer, the Russian chemist Lev Aleksandrovich Chugaev (1873–1922), who first reported the reaction sequence in 1899.
Phosphite ozonides, (RO) 3 PO 3, are used in the production of singlet oxygen. They are made by ozonizing a phosphite ester in dichloromethane at low temperatures, and decompose to yield singlet oxygen and a phosphate ester: [6] [7] (RO) 3 P + O 3 → (RO) 3 PO 3 (RO) 3 PO 3 → (RO) 3 PO + 1 O 2