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  2. Gas constant - Wikipedia

    en.wikipedia.org/wiki/Gas_constant

    Using his extensive measurements of the properties of gases, [6] [7] Mendeleev also calculated it with high precision, within 0.3% of its modern value. [ 8 ] The gas constant occurs in the ideal gas law: P V = n R T = m R s p e c i f i c T {\displaystyle PV=nRT=mR_{\rm {specific}}T} where P is the absolute pressure , V is the volume of gas, n ...

  3. Van der Waals equation - Wikipedia

    en.wikipedia.org/wiki/Van_der_Waals_equation

    Here because is a multivalued function, the integral must be divided into 3 parts corresponding to the 3 real roots of the vdW equation in the form, (,) (this can be visualized most easily by imagining Fig. 1 rotated ); the result is a special case of material equilibrium. [66]

  4. Stoichiometry - Wikipedia

    en.wikipedia.org/wiki/Stoichiometry

    324.41 g FeCl 3, 102.25 g H 2 S, 207.89 g Fe 2 S 3, 218.77 g HCl. Suppose 90.0 g of FeCl 3 reacts with 52.0 g of H 2 S. To find the limiting reagent and the mass of HCl produced by the reaction, we change the above amounts by a factor of 90/324.41 and obtain the following amounts: 90.00 g FeCl 3, 28.37 g H 2 S, 57.67 g Fe 2 S 3, 60.69 g HCl

  5. Proton radius puzzle - Wikipedia

    en.wikipedia.org/wiki/Proton_radius_puzzle

    Historically the proton charge radius was measured by two independent methods, which converged to a value of about 0.877 femtometres (1 fm = 10 −15 m). This value was challenged by a 2010 experiment using a third method, which produced a radius about 4% smaller than this, at 0.842 femtometres. [ 2 ]

  6. Bridgman's thermodynamic equations - Wikipedia

    en.wikipedia.org/wiki/Bridgman's_thermodynamic...

    This method of rewriting the partial derivative was described by Bridgman (and also Lewis & Randall), and allows the use of the following collection of expressions to express many thermodynamic equations. For example from the equations below we have: = and =

  7. Glossary of chemistry terms - Wikipedia

    en.wikipedia.org/wiki/Glossary_of_chemistry_terms

    A non-SI, metric unit of length equal to 1010 metre, i.e. 1 ⁄ 10000000000 of a metre or 0.1 nanometre. The angstrom is commonly used in the natural sciences to express microscopic or atomic-scale distances, including the sizes of atomic nuclei, wavelengths of electromagnetic radiation, and lengths of chemical bonds (e.g. the covalent ...

  8. Marcus theory - Wikipedia

    en.wikipedia.org/wiki/Marcus_theory

    In outer sphere redox reactions no bonds are formed or broken; only an electron transfer (ET) takes place. A quite simple example is the Fe 2+ /Fe 3+ redox reaction, the self exchange reaction which is known to be always occurring in an aqueous solution containing the aquo complexes [Fe(H 2 O) 6] 2+ and [Fe(H 2 O)6] 3+.

  9. Rademacher complexity - Wikipedia

    en.wikipedia.org/wiki/Rademacher_complexity

    Gaussian complexity is a similar complexity with similar physical meanings, and can be obtained from the Rademacher complexity using the random variables instead of , where are Gaussian i.i.d. random variables with zero-mean and variance 1, i.e. (,). Gaussian and Rademacher complexities are known to be equivalent up to logarithmic factors.