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The Journal of Electroanalytical Chemistry is a peer-reviewed scientific journal on electroanalytical chemistry, published by Elsevier twice per month. It was originally established in 1959 under the current name, but was known as the Journal of Electroanalytical Chemistry and Interfacial Electrochemistry from 1967 to 1991.
The electroactive ion present in the interfacial region experiences the interfacial potential and electrostatic work is done on the ion by a part of the interfacial electric field. It is charge transfer coefficient that signifies this part that is utilized in activating the ion to the top of the free energy barrier.
Interfacial DLs are most apparent in systems with a large surface-area-to-volume ratio, such as a colloid or porous bodies with particles or pores (respectively) on the scale of micrometres to nanometres. However, DLs are important to other phenomena, such as the electrochemical behaviour of electrodes.
[1] [2] [3] There is a common source of all these effects—the so-called interfacial 'double layer' of charges. Influence of an external force on the diffuse layer generates tangential motion of a fluid with respect to an adjacent charged surface. This force might be electric, pressure gradient, concentration gradient, or gravity.
Quantum photoelectrochemistry calculation of photoinduced interfacial electron transfer in a dye-sensitized solar cell. Quantum photoelectrochemistry in particular provides fundamental insight into basic light-harvesting and photoinduced electro-optical processes in several emerging solar energy conversion technologies for generation of both ...
An interfacial potential is thus defined as a charge located at the common boundary between two phases (for example, an amino acid such as glutamate on the surface of a protein can have its side chain carboxylic acid deprotonated in environments with pH greater than 4.1 to produce a charged amino acid at the surface, which would create an ...
Randles circuit schematic. In electrochemistry, a Randles circuit is an equivalent electrical circuit that consists of an active electrolyte resistance R S in series with the parallel combination of the double-layer capacitance C dl and an impedance (Z w) of a faradaic reaction.
Double-layer capacitance is the important characteristic of the electrical double layer [1] [2] which appears at the interface between a surface and a fluid (for example, between a conductive electrode and an adjacent liquid electrolyte).