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Bis(trimethylsilyl) sulfide is the chemical compound with the formula ((CH 3) 3 Si) 2 S. Often abbreviated ( tms ) 2 S, this colourless, vile-smelling liquid is a useful aprotic source of "S 2− " in chemical synthesis.
A trimethylsilyl group (abbreviated TMS) is a functional group in organic chemistry. This group consists of three methyl groups bonded to a silicon atom [−Si(CH 3 ) 3 ], which is in turn bonded to the rest of a molecule.
Bis(trimethylsilyl)acetamide (BSA) is an organosilicon compound with the formula MeC(OSiMe 3)NSiMe 3 (Me = CH 3). It is a colorless liquid that is soluble in diverse organic solvents, but reacts rapidly with moisture and solvents containing OH and NH groups .
Bis(trimethylsilyl)amine (also known as hexamethyldisilazane and HMDS) is an organosilicon compound with the molecular formula [(CH 3) 3 Si] 2 NH. The molecule is a derivative of ammonia with trimethylsilyl groups in place of two hydrogen atoms.
Lithium, sodium, and potassium bis(trimethylsilyl)amides are commercially available. When free of solvent, the lithium [5] and sodium [6] complexes are trimeric, and ...
Bis(trimethylsilyl)acetylene (BTMSA) is an organosilicon compound with the formula Me 3 SiC≡CSiMe 3 (Me = methyl). It is a crystalline solid that melts slightly above room temperature and is soluble in organic solvents.
N,O-Bis(trimethylsilyl)trifluoroacetamide (BSTFA) is an organosilicon compound. It is a colorless liquid that is very sensitive to traces of water or alcohols. It is often used to convert hydroxyl groups to trimethylsilyl ether groups (Me = CH 3): ROH + CF 3 C(OSiMe 3)NSiMe 3 → CF 3 C(O)NH(SiMe 3) + ROSiMe 3
Bis(trimethylsilyl)sulfur diimide is the organosulfur compound with the formula S(NSiMe 3) 2 (Me = CH 3). A colorless liquid, it is a diaza analogue of sulfur dioxide, i.e., a sulfur diimide. It is a reagent in the synthesis of sulfur nitrides. For example, it is a precursor to C 2 (N 2 S) 2. [1]
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