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The reaction has been the subject of several literature reviews. [1] [2] [3] The Nef reaction: 1. Salt of a nitroalkane 3. Ketone 4. Nitrous oxide. The reaction was reported in 1894 by the chemist John Ulric Nef, [4] who treated the sodium salt of nitroethane with sulfuric acid resulting in an 85–89% yield of nitrous oxide and at least 70% ...
Nitroethane is produced industrially by treating propane with nitric acid at 350–450 °C. This exothermic reaction produces four industrially significant nitroalkanes: nitromethane, nitroethane, 1-nitropropane, and 2-nitropropane. The reaction involves free radicals, such as CH 3 CH 2 CH 2 O., which arise via homolysis of the corresponding ...
A neutralization reaction is a type of double replacement reaction. A neutralization reaction occurs when an acid reacts with an equal amount of a base. This reaction usually produces a salt. One example, hydrochloric acid reacts with disodium iron tetracarbonyl to produce the iron dihydride: 2 HCl + Na 2 Fe(CO) 4 → 2 NaCl + H 2 Fe(CO) 4
In the lab, phenyl-2-nitropropene is produced by the reaction of benzaldehyde and nitroethane in the presence of a basic catalyst like n-butylamine.The reaction is a nitroaldol reaction, and is a variant of a Knoevenagel condensation reaction, which is one of a broader class of reactions called Henry condensations, or simply Henry reactions.
The reaction produces fragments from the parent alkane, creating a diverse mixture of products; for instance, nitromethane, nitroethane, 1-nitropropane, and 2-nitropropane are produced by treating propane with nitric acid in the gas phase (e.g. 350–450 °C and 8–12 atm).
Nitroethene can react at the 2π electron source in a [3+2] cycloaddition with nitrones. [5] [6] Nitroethylene is also reactive in domino-cycloaddition processes. For example, they can initially react with a chiral vinyl ether, and then react in a [3+2] cycloaddition with an electron deficient alkene such as dimethyl fumarate. The reactions are ...
With the reaction involving the addition of an acidic carbon nucleophile to a carbon-heteroatom double bond, the nitro-Mannich reaction is related to some of the most fundamental carbon-carbon bond forming reactions in organic chemistry, including the aldol reaction, [2] Henry reaction (nitro-aldol reaction) [3] and Mannich reaction. [4]
Cyclic phosphorylation is important to create ATP and maintain NADPH in the right proportion for the light-independent reactions. The net-reaction of all light-dependent reactions in oxygenic photosynthesis is: 2 H 2 O + 2 NADP + + 3ADP + 3P i → O 2 + 2 H + + 2NADPH + 3ATP. PSI and PSII are light-harvesting complexes.