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In organic chemistry, a carbanion is an anion in which carbon is negatively charged. [1] [failed verification]Formally, a carbanion is the conjugate base of a carbon acid: . R 3 CH + B − → R 3 C − + HB
Thus, for example, the stable carbonate anion corresponds to the extremely unstable neutral carbon trioxide CO 3; [2] oxalate C 2 O 2− 4 correspond to the even less stable 1,2-dioxetanedione C 2 O 4; [3] and the stable croconate anion C 5 O 2− 5 corresponds to the neutral cyclopentanepentone C 5 O 5, which has been detected only in trace ...
Note: All measurements given are in picometers (pm). For more recent data on covalent radii see Covalent radius.Just as atomic units are given in terms of the atomic mass unit (approximately the proton mass), the physically appropriate unit of length here is the Bohr radius, which is the radius of a hydrogen atom.
For each atom, the column marked 1 is the first ionization energy to ionize the neutral atom, the column marked 2 is the second ionization energy to remove a second electron from the +1 ion, the column marked 3 is the third ionization energy to remove a third electron from the +2 ion, and so on.
The lowest oxidation state is −5, as for boron in Al 3 BC [3] and gallium in pentamagnesium digallide (Mg 5 Ga 2). In Stock nomenclature , which is commonly used for inorganic compounds, the oxidation state is represented by a Roman numeral placed after the element name inside parentheses or as a superscript after the element symbol, e.g ...
Electron affinity can be defined in two equivalent ways. First, as the energy that is released by adding an electron to an isolated gaseous atom. The second (reverse) definition is that electron affinity is the energy required to remove an electron from a singly charged gaseous negative ion.
Such an atom has the following electron configuration: s 2 p 5; this requires only one additional valence electron to form a closed shell. To form an ionic bond, a halogen atom can remove an electron from another atom in order to form an anion (e.g., F −, Cl −, etc.). To form a covalent bond, one electron from the halogen and one electron ...
The latter trend results from the outer electron shell being progressively farther from the nucleus, with the addition of one inner shell per row as one moves down the column. The nth ionization energy refers to the amount of energy required to remove the most loosely bound electron from the species having a positive charge of (n − 1). For ...