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A corresponding partition coefficient for ionizable compounds, abbreviated log P I, is derived for cases where there are dominant ionized forms of the molecule, such that one must consider partition of all forms, ionized and un-ionized, between the two phases (as well as the interaction of the two equilibria, partition and ionization).
The three lines on this diagram meet at that point. Green line Chromate and hydrogen chromate have equal concentrations. Setting [CrO 2− 4] equal to [HCrO − 4] in eq. 1, [H +] = 1 / K 1 , or pH = log K 1. This relationship is independent of pCr, so it requires a vertical line to be drawn on the predominance diagram. Red line
pH partition is the tendency for acids to accumulate in basic fluid compartments, and bases to accumulate in acidic compartments. The reason for this phenomenon is that acids become negatively electric charged in basic fluids, as they donate a proton. On the other hand, bases become positively electric charged in acid fluids, as they receive a ...
Similar to Pourbaix diagrams for the speciation of redox species as a function of the redox potential and the pH, ionic partition diagrams indicate in which phase an acid or a base is predominantly present in a biphasic system as a function of the Galvani potential difference between the two phases and the pH of the aqueous solution. One of the ...
Where K d is called the distribution coefficient or the partition coefficient. Concentration of X in solvent A/concentration of X in solvent B=Kď If C 1 denotes the concentration of solute X in solvent A & C 2 denotes the concentration of solute X in solvent B; Nernst's distribution law can be expressed as C 1 /C 2 = K d. This law is only ...
Coefficients for partition between given gas phase and solvent wet/dry solvent c e s a b l source w Butan-1-ol -0.095 0.262 1.396 3.405 2.565
‡ Second column of table indicates solubility at each given temperature in volume of CO 2 as it would be measured at 101.3 kPa and 0 °C per volume of water. The solubility is given for "pure water", i.e., water which contain only CO 2. This water is going to be acidic. For example, at 25 °C the pH of 3.9 is expected (see carbonic acid).
The distribution coefficient (K c which coincides with partition coefficient) of atabrine varied by the composition of the solvent system and the pH of the buffer. In the next article, Craig was inspired by the work of Martin and Synge with partition chromatography to develop an apparatus that would separate compounds based on their ...