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Dimethyldichlorosilane is a tetrahedral organosilicon compound with the formula Si(CH 3) 2 Cl 2. At room temperature it is a colorless liquid that readily reacts with water to form both linear and cyclic Si-O chains. Dimethyldichlorosilane is made on an industrial scale as the principal precursor to dimethylsilicone and polysilane compounds.
Stock and Somieski completed the hydrolysis of dichlorosilane by putting the solution of H 2 SiCl 2 in benzene in brief contact with a large excess of water. [3] [5] A large-scale hydrolysis was done in a mixed ether/alkane solvent system at 0 °C, which gave a mixture of volatile and nonvolatile [H 2 SiO] n.
2 ((CH 3) 3 SiCl + H 2 O → [(CH 3) 3 Si] 2 O + 2 HCl. The analogous reaction of dimethyldichlorosilane gives siloxane polymers or rings: n (CH 3) 2 SiCl 2 + n H 2 O → [(CH 3) 2 SiO] n + 2n HCl. Many compounds containing Si-Cl bonds can be converted to hydrides using lithium aluminium hydride, This kind of conversion was demonstrated for the ...
Hexamethyldisilazane lithium salt. ... (Si(CH 3) 3) 2 Molar mass: 167.33 g·mol −1 Appearance White solid Density: 0.86 g/cm 3 at 25 °C
[1] 2 CH 3 Cl + Si → (CH 3) 4−n SiCl n + other products. While this reaction is the standard in industrial silicone production and is nearly identical to the first direct synthesis of methyltrichlorosilane, the overall process is inefficient with respect to methyltrichlorosilane. [2]
The chemical formula of PDMS is CH 3 [Si(CH 3) 2 O] n Si(CH 3) 3, where n is the number of repeating monomer [Si(CH 3) 2 O] units. [4] Industrial synthesis can begin from dimethyldichlorosilane and water by the following net reaction: n Si(CH 3) 2 Cl 2 + (n+1) H 2 O → HO[Si(CH 3) 2 O] n H + 2n HCl. The polymerization reaction evolves ...
This group consists of three methyl groups bonded to a silicon atom [−Si(CH 3) 3], which is in turn bonded to the rest of a molecule. This structural group is characterized by chemical inertness and a large molecular volume , which makes it useful in a number of applications.
1 g/cm 3 = 1000 kg/m 3; megagram (metric ton) per cubic metre (Mg/m 3) In US customary units density can be stated in: Avoirdupois ounce per cubic inch (1 g/cm 3 ≈ 0.578036672 oz/cu in) Avoirdupois ounce per fluid ounce (1 g/cm 3 ≈ 1.04317556 oz/US fl oz = 1.04317556 lb/US fl pint) Avoirdupois pound per cubic inch (1 g/cm 3 ≈ 0.036127292 ...