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Nickel nitrate is the inorganic compound Ni(NO 3) 2 or any hydrate thereof. In the hexahydrate, the nitrate anions are not bonded to nickel. Other hydrates have also been reported: Ni(NO 3) 2. 9H 2 O, Ni(NO 3) 2. 4H 2 O, and Ni(NO 3) 2. 2H 2 O. [3] It is prepared by the reaction of nickel oxide with nitric acid: NiO + 2 HNO 3 + 5 H 2 O → Ni ...
In the NO − 3 anion, the oxidation state of the central nitrogen atom is V (+5). This corresponds to the highest possible oxidation number of nitrogen. Nitrate is a potentially powerful oxidizer as evidenced by its explosive behaviour at high temperature when it is detonated in ammonium nitrate (NH 4 NO 3), or black powder, ignited by the shock wave of a primary explosive.
Nickel hydrazine nitrate (NHN), (chemical formula: [Ni(N 2 H 4) 3](NO 3) 2 is an energetic material having explosive properties in between that of primary explosive and a secondary explosive. [1] It is a salt of a coordination compound of nickel with a reaction equation of 3N 2 H 4 ·H 2 O + Ni(NO 3) 2 →〔Ni(N 2 H 4) 3 〕(NO 3) 2 ＋ 3H 2 O [2]
Magnesium nitrate refers to inorganic compounds with the formula Mg(NO 3) 2 (H 2 O) x, where x = 6, 2, and 0. All are white solids. [2] The anhydrous material is hygroscopic, quickly forming the hexahydrate upon standing in air. All of the salts are very soluble in both water and ethanol.
2 HNO 3 + Na 2 CO 3 → 2 NaNO 3 + H 2 O + CO 2 HNO 3 + NaHCO 3 → NaNO 3 + H 2 O + CO 2. or also by neutralizing it with sodium hydroxide (however, this reaction is very exothermic): HNO 3 + NaOH → NaNO 3 + H 2 O. or by mixing stoichiometric amounts of ammonium nitrate and sodium hydroxide, sodium bicarbonate or sodium carbonate: NH 4 NO 3 ...
The method is illustrated by the route to β-Cu(NO 3) 2: Cu + 2 N 2 O 4 → Cu(NO 3) 2 + 2 NO. Many metals, metal halides, and metal carbonyls undergo similar reactions, but the product formulas can be deceptive. For example from chromium one obtains Cr(NO 3) 3 (N 2 O 4) 2, which was shown to be the salt (NO +) 2 [Cr(NO 3) 5] 2-. [15]
name formula ratio NO 3:NO 2. mw system space group unit cell Å volume density properties references [Cr(NH 3) 5 (NO 2)] ·(NO 3) 2 [2]trans-dinitrotetraamminecobalt(III) nitrate monohydrate
The compound can be prepared by treating nickel or nickel(II) carbonate with acetic acid: . NiCO 3 + 2 CH 3 CO 2 H + 3 H 2 O → Ni(CH 3 CO 2) 2 ·4 H 2 O + CO 2. The mint-green tetrahydrate has been shown by X-ray crystallography to adopt an octahedral structure, the central nickel centre being coordinated by four water molecules and two acetate ligands. [5]