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A specialized application of electrolysis involves the growth of conductive crystals on one of the electrodes from oxidized or reduced species that are generated in situ. The technique has been used to obtain single crystals of low-dimensional electrical conductors, such as charge-transfer salts and linear chain compounds .
A video describing the process of electrolytic reduction used in a display at The Children's Museum of Indianapolis within the Treasures of the Earth exhibit. The video describes the electrolytic process as it is occurring on Captain Kidd's Cannon, which is on display and currently undergoing the electrolytic process.
Important examples of electrolysis are the decomposition of water into hydrogen and oxygen, and bauxite into aluminum and other chemicals. Electroplating (e.g., of copper, silver, nickel, or chromium) is done using an electrolytic cell. Electrolysis is a technique that uses a direct electric current (DC).
The chloralkali process (also chlor-alkali and chlor alkali) is an industrial process for the electrolysis of sodium chloride (NaCl) solutions. It is the technology used to produce chlorine and sodium hydroxide (caustic soda), [ 1 ] which are commodity chemicals required by industry.
Separately pressurised into convenient 'tanks' or 'gas bottles', hydrogen can be used for oxyhydrogen welding and other applications, as the hydrogen / oxygen flame can reach approximately 2,800°C. Water electrolysis requires a minimum potential difference of 1.23 volts, although at that voltage external heat is also required. Typically 1.5 ...
Proton exchange membrane (PEM) electrolysis is the electrolysis of water in a cell equipped with a solid polymer electrolyte (SPE) [3] that is responsible for the conduction of protons, separation of product gases, and electrical insulation of the electrodes. The PEM electrolyzer was introduced to overcome the issues of partial load, low ...
Conversely, non-spontaneous electrochemical reactions can be driven forward by the application of a current at sufficient voltage. The electrolysis of water into gaseous oxygen and hydrogen is a typical example. The relation between the equilibrium constant, K, and the Gibbs free energy for an electrochemical cell is expressed as follows:
Electrolysis; Electrowinning, the extraction of metal from ores [2] Electrorefining, the purification of metals. [2] Metal powder production by electrodeposition is included in this category, or sometimes electrowinning, or a separate category depending on application. [2] Electroplating, the deposition of a layer of one metal on another [2]