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Isotopomers or isotopic isomers are isomers with isotopic atoms, having the same number of each isotope of each element but differing in their positions in the molecule. The result is that the molecules are either constitutional isomers or stereoisomers solely based on isotopic location.
In chemistry, isomers are molecules or polyatomic ions with identical molecular formula – that is, the same number of atoms of each element – but distinct arrangements of atoms in space. [1] Isomerism refers to the existence or possibility of isomers.
The term isotopes (originally also isotopic elements, [4] now sometimes isotopic nuclides [5]) is intended to imply comparison (like synonyms or isomers). For example, the nuclides 12 6 C, 13 6 C, 14 6 C are isotopes (nuclides with the same atomic number but different mass numbers [6]), but 40 18 Ar, 40 19 K, 40 20 Ca are isobars (nuclides with ...
Hydrogen (1 H) has three naturally occurring isotopes: 1 H, 2 H, and 3 H. 1 H and 2 H are stable, while 3 H has a half-life of 12.32(2) years. [3] [nb 1] Heavier isotopes also exist; all are synthetic and have a half-life of less than 1 zeptosecond (10 −21 s). [4] [5] Of these, 5 H is the least stable, while 7 H is the most.
A nuclear isomer is a metastable state of an atomic nucleus, in which one or more nucleons (protons or neutrons) occupy excited state levels (higher energy levels). ). "Metastable" describes nuclei whose excited states have half-lives 100 to 1000 times longer than the half-lives of the excited nuclear states that decay with a "prompt" half life (ordinarily on the order of 10
The cis isomer in this case has a boiling point of 60.3 °C, while the trans isomer has a boiling point of 47.5 °C. [6] In the cis isomer the two polar C–Cl bond dipole moments combine to give an overall molecular dipole, so that there are intermolecular dipole–dipole forces (or Keesom forces), which add to the London dispersion forces and ...
In chemistry, a structural isomer (or constitutional isomer in the IUPAC nomenclature [1]) of a compound is another compound whose molecule has the same number of atoms of each element, but with logically distinct [clarification needed] bonds between them. [2] [3] The term metamer was formerly used for the same concept. [4]
See Isotope#Notation for an explanation of the notation used for different nuclide or isotope types. Nuclear isomers are members of a set of nuclides with equal proton number and equal mass number (thus making them by definition the same isotope), but different states of excitation. An example is the two states of the single isotope 99 43 Tc