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  2. Dissociation (chemistry) - Wikipedia

    en.wikipedia.org/wiki/Dissociation_(chemistry)

    The degree of dissociation in gases is denoted by the symbol α, where α refers to the percentage of gas molecules which dissociate. Various relationships between K p and α exist depending on the stoichiometry of the equation. The example of dinitrogen tetroxide (N 2 O 4) dissociating to nitrogen dioxide (NO 2) will be taken.

  3. Dissociative adsorption - Wikipedia

    en.wikipedia.org/wiki/Dissociative_adsorption

    The dissociation involves cleaving of the molecular bonds in the adsorbate, and formation of new bonds with the substrate. Breaking the atomic bonds of the dissociating molecule requires a large amount of energy, thus dissociative adsorption is an example of chemisorption , where strong adsorbate-substrate bonds are created. [ 1 ]

  4. Dissociation constant - Wikipedia

    en.wikipedia.org/wiki/Dissociation_constant

    In chemistry, biochemistry, and pharmacology, a dissociation constant (K D) is a specific type of equilibrium constant that measures the propensity of a larger object to separate (dissociate) reversibly into smaller components, as when a complex falls apart into its component molecules, or when a salt splits up into its component ions.

  5. Bond cleavage - Wikipedia

    en.wikipedia.org/wiki/Bond_cleavage

    In chemistry, bond cleavage, or bond fission, is the splitting of chemical bonds. This can be generally referred to as dissociation when a molecule is cleaved into two or more fragments. [1] In general, there are two classifications for bond cleavage: homolytic and heterolytic, depending on the nature of the process.

  6. Acid dissociation constant - Wikipedia

    en.wikipedia.org/wiki/Acid_dissociation_constant

    In chemistry, an acid dissociation constant (also known as acidity constant, or acid-ionization constant; denoted ⁠ ⁠) is a quantitative measure of the strength of an acid in solution. It is the equilibrium constant for a chemical reaction + +

  7. Size consistency and size extensivity - Wikipedia

    en.wikipedia.org/wiki/Size_consistency_and_size...

    In quantum chemistry, size consistency and size extensivity are concepts relating to how the behaviour of quantum-chemistry calculations changes with the system size. Size consistency (or strict separability) is a property that guarantees the consistency of the energy behaviour when interaction between the involved molecular subsystems is nullified (for example, by distance).

  8. Dissociative recombination - Wikipedia

    en.wikipedia.org/wiki/Dissociative_recombination

    Dissociative recombination is a chemical process in which a positive polyatomic ion recombines with an electron, and as a result, the neutral molecule dissociates. [1] This reaction is important for interstellar and atmospheric chemistry.

  9. Dissociation - Wikipedia

    en.wikipedia.org/wiki/Dissociation

    Dissociation, in the wide sense of the word, is an act of disuniting or separating a complex object into parts. Dissociation may also refer to: Dissociation (chemistry) , general process in which molecules or ionic compounds (complexes, or salts) split into smaller particles, usually in a reversible manner