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Currently the efficiency for hydrogen production by water electrolysis of electricity amounts to 75 to 85% [19] with potential up to 93% until 2030. [25] Efficiency for methanol synthesis of hydrogen and carbon dioxide currently is 79 to 80%. [19] Thus the efficiency for production of methanol from electricity and carbon dioxide is about 59 to 78%.
Methanol and ethanol can both be derived from fossil fuels, biomass, or from carbon dioxide and water. Ethanol has most commonly been produced through fermentation of sugars, and methanol has most commonly been produced from synthesis gas, but there are more modern ways to obtain these fuels. Enzymes can be used instead of fermentation.
The fuel cartridge stores the methanol fuel. Depending on the system design either 100% methanol (IMPCA industrial standard) or a mixture of methanol with up to 40 vol% water is usually used as fuel for the RMFC system. 100% methanol results in lower fuel consumption than water-methanol mixture (Premix) but goes along with higher fuel cell system complexity for condensing of cathode moisture.
providing water along with methanol would make the fuel supply more cumbersome, so water has to be recycled in a loop; CO 2 has to be removed from the solution flow exiting the fuel cell; water in the anodic loop is slowly consumed by reaction and drag; it is necessary to recover water from the cathodic side to maintain steady operation.
In 2007 ethanol was priced at 3 to 4 dollars per gallon (0.8 to 1.05 dollars per liter) at the pump, while methanol made from natural gas remains at 47 cents per gallon (12.5 cents per liter) in bulk, not at the pump. Presently there are no operating gas stations in California supplying methanol in their pumps. Rep.
A mixture of water and methanol with a molar concentration ratio (water:methanol) of 1.0 - 1.5 is pressurized to approximately 20 bar, vaporized and heated to a temperature of 250 - 360 °C. The hydrogen that is created is separated through the use of Pressure swing adsorption or a hydrogen-permeable membrane made of polymer or a palladium alloy.
Carbon Recycling International (CRI) is an Icelandic limited liability company which has developed a technology designed to produce renewable methanol, also known as e-methanol, from carbon dioxide and hydrogen, using water electrolysis or, alternatively, hydrogen captured from industrial waste gases.
Water 220.64 bar, 373.8 °C [citation needed] [clarification needed] 1.968: 0.708: Kinetic energy penetrator [clarification needed] 1.9: 30: battery, Lithium–Sulfur [15] 1.80 [16] 1.26: battery, Fluoride-ion [citation needed] 1.7: 2.8: battery, Hydrogen closed cycle H fuel cell [17] 1.62: Hydrazine decomposition (as monopropellant) 1.6: 1.6