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Commercially available nitric acid is an azeotrope with water at a concentration of 68% HNO 3. This solution has a boiling temperature of 120.5 °C (249 °F) at 1 atm. It is known as "concentrated nitric acid". The azeotrope of nitric acid and water is a colourless liquid at room temperature.
Temperature-dependency of the heats of vaporization for water, methanol, benzene, and acetone. In thermodynamics, the enthalpy of vaporization (symbol ∆H vap), also known as the (latent) heat of vaporization or heat of evaporation, is the amount of energy that must be added to a liquid substance to transform a quantity of that substance into a gas.
The rule, however, has some exceptions. For example, the entropies of vaporization of water, ethanol, formic acid and hydrogen fluoride are far from the predicted values. The entropy of vaporization of XeF 6 at its boiling point has the extraordinarily high value of 136.9 J/(K·mol). [4]
The Antoine equation is a class of semi-empirical correlations describing the relation between vapor pressure and temperature for pure substances. The Antoine equation is derived from the Clausius–Clapeyron relation. The equation was presented in 1888 by the French engineer Louis Charles Antoine (1825–1897). [1]
L is the latent heat of vaporization at the temperature T, T C is the critical temperature, L 0 is the parameter that is equal to the heat of vaporization at zero temperature (T → 0), tanh is the hyperbolic tangent function. This equation was obtained in 1955 by Yu. I. Shimansky, at first empirically, and later derived
The resultant nitric acid was then used as a source of nitrate (NO 3 −) in the reaction + + + which may take place in the presence of water or another proton acceptor. It was developed by Norwegian industrialist and scientist Kristian Birkeland along with his business partner Sam Eyde in 1903, [ 2 ] based on a method used by Henry Cavendish ...
Principle of a group-contribution method. The Joback method is a group-contribution method.These kinds of methods use basic structural information of a chemical molecule, like a list of simple functional groups, add parameters to these functional groups, and calculate thermophysical and transport properties as a function of the sum of group parameters.
During nitromethane combustion, nitric oxide (NO) is one of the major emission products along with CO 2 and H 2 O. [16] Nitric oxide contributes to air pollution, acid rain, and ozone layer depletion. Recent (2020) studies [17] suggest the correct stoichiometric equation for the burning of nitromethane is: 4 CH 3 NO 2 + 5 O 2 → 4 CO 2 + 6 H 2 ...