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Thus, the atomic mass of a carbon-12 atom is 12 Da by definition, but the relative isotopic mass of a carbon-12 atom is simply 12. The sum of relative isotopic masses of all atoms in a molecule is the relative molecular mass. The atomic mass of an isotope and the relative isotopic mass refers to a certain specific isotope of an element.
With the discovery of oxygen isotopes in 1929, a situation arose where chemists based their calculations on the average atomic mass (atomic weight) of oxygen whereas physicists used the mass of the predominant isotope of oxygen, oxygen-16. This discrepancy became undesired and a unification between the chemistry and physics was necessary. [13]
The standard atomic weight (A r °(Cu)) for copper is the average, weighted by their natural abundance, and then divided by the atomic mass constant m u. [ 1 ] The standard atomic weight of a chemical element (symbol A r °(E) for element "E") is the weighted arithmetic mean of the relative isotopic masses of all isotopes of that element ...
The mass of an atom or a molecule is referred to as the atomic mass. The atomic mass is used to find the average mass of elements and molecules and to solve stoichiometry problems. The name "atomic mass" is used for historical reasons, and originates from the fact that chemistry was the first science to investigate the same physical objects on ...
The relative atomic mass (a weighted average, weighted by mole-fraction abundance figures) of these isotopes is the atomic weight listed for the element in the periodic table. The abundance of an isotope varies from planet to planet, and even from place to place on the Earth, but remains relatively constant in time (on a short-term scale).
The mass number gives an estimate of the isotopic mass measured in atomic mass units (u). For 12 C, the isotopic mass is exactly 12, since the atomic mass unit is defined as 1/12 of the mass of 12 C. For other isotopes, the isotopic mass is usually within 0.1 u of the mass number.
The longest-lived of these isotopes, and the most relevantly studied, are 90 Sr with a half-life of 28.9 years, 85 Sr with a half-life of 64.853 days, and 89 Sr (89 Sr) with a half-life of 50.57 days. All other strontium isotopes have half-lives shorter than 50 days, most under 100 minutes.
The molar mass of atoms of an element is given by the relative atomic mass of the element multiplied by the molar mass constant, M u ≈ 1.000 000 × 10 −3 kg/mol ≈ 1 g/mol. For normal samples from Earth with typical isotope composition, the atomic weight can be approximated by the standard atomic weight [2] or the conventional atomic weight.
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