Search results
Results from the WOW.Com Content Network
Capillary condensation in pores with r<10 nm is often difficult to describe using the Kelvin equation. This is because the Kelvin equation underestimates the size of the pore radius when working on the nanometer scale.
The Kelvin equation describes the change in vapour pressure due to a curved liquid–vapor interface, such as the surface of a droplet. The vapor pressure at a convex curved surface is higher than that at a flat surface. The Kelvin equation is dependent upon thermodynamic principles and does not allude to special properties of materials.
The Köhler equation relates the saturation ratio over an aqueous solution droplet of fixed dry mass to its wet diameter as [4]: = (), with: S {\displaystyle S} = saturation ratio over the droplet surface defined as S = p w / p w 0 {\textstyle S=p_{w}/p_{w}^{0}} , where p w {\textstyle p_{w}} is the water vapor pressure of the solution ...
The technique is closely related to using gas adsorption to measure pore sizes, but uses the Gibbs–Thomson equation rather than the Kelvin equation.They are both particular cases of the Gibbs Equations of Josiah Willard Gibbs: the Kelvin equation is the constant temperature case, and the Gibbs–Thomson equation is the constant pressure case. [1]
The defining equation for a capillary surface is called the stress balance equation, [2] which can be derived by considering the forces and stresses acting on a small volume that is partly bounded by a capillary surface. For a fluid meeting another fluid (the "other" fluid notated with bars) at a surface , the equation reads
At high partial pressure in the adsorption/desorption the Kelvin equation gives the pore size distribution of the sample. In mercury porosimetry, the mercury is forced into the aerogel porous system to determine the pores' size, but this method is highly inefficient since the solid frame of aerogel will collapse from the high compressive force.
The surface energy of a liquid may be measured by stretching a liquid membrane (which increases the surface area and hence the surface energy). In that case, in order to increase the surface area of a mass of liquid by an amount, δA, a quantity of work, γ δA, is needed (where γ is the surface energy density of the liquid).
The interfacial (surface) tension, St, (dyne cm −1), can be calculated by applying the equation of capillary rise method (when the contact angle Ө → 0): = where: h (cm) is the height of Hg column above the Hg meniscus in the capillary; r (cm) is the radius of capillary