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Selenium tetrafluoride (Se F 4) is an inorganic compound.It is a colourless liquid that reacts readily with water. It can be used as a fluorinating reagent in organic syntheses (fluorination of alcohols, carboxylic acids or carbonyl compounds) and has advantages over sulfur tetrafluoride in that milder conditions can be employed and it is a liquid rather than a gas.
Seleninyl fluoride can be produced by the reaction of selenium oxychloride and potassium fluoride. [3] 2 KF + SeOCl 2 → 2 KCl + SeOF 2. It can also be produced by the reaction of selenium tetrafluoride with water or selenium dioxide. [2] SeF 4 + H 2 O → SeOF 2 + 2 HF SeF 4 + SeO 2 → 2 SeOF 2
Pentafluoroselenium hypofluorite can be produced from the reaction of selenium dioxide or selenium oxychloride with fluorine gas in the presence of silver difluoride catalyst. However, the reaction yield is low (14% [ 3 ] ), and it is hard to purify due to large amount of SeF 6 byproduct.
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Dinitrogen tetrafluoride, N 2 F 4 (Tetrafluorohydrazine) Einsteinium tetrafluoride, EsF 4; Germanium tetrafluoride, GeF 4; Hafnium tetrafluoride, HfF 4; Iridium tetrafluoride, IrF 4; Iron tetrafluoride, FeF 4; Krypton tetrafluoride, KrF 4 (predicted) Lead tetrafluoride, PbF 4; Manganese tetrafluoride, MnF 4; Mercury tetrafluoride, HgF 4 ...
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A convenient, safe method for generating TFE is the pyrolysis of the sodium salt of pentafluoropropionic acid: [6]. C 2 F 5 CO 2 Na → C 2 F 4 + CO 2 + NaF. The depolymerization reaction – vacuum pyrolysis of PTFE at 650–700 °C (1,200–1,290 °F) in a quartz vessel – is a traditional laboratory synthesis of TFE.
Selenium tetrachloride is the inorganic compound composed with the formula SeCl 4. This compound exists as yellow to white volatile solid. This compound exists as yellow to white volatile solid. It is one of two commonly available selenium chlorides , the other example being selenium monochloride , Se 2 Cl 2 .