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Solid properties Std enthalpy change of formation, Δ f H o solid-1675.7 kJ/mol Standard molar entropy, S o solid: 50.92 J/(mol K) Heat capacity, c p: 89.7248 J/(mol K) Liquid properties Std enthalpy change of formation, Δ f H o liquid-1620.57 kJ/mol Standard molar entropy, S o liquid: 67.24 J/(mol K) Heat capacity, c p: 192.5 J/(mol K) Gas ...
Structure of an octahedral metal aquo complex. Chromium(II) ion in aqueous solution. Most aquo complexes are mono-nuclear, with the general formula [M(H 2 O) 6] n+, with n = 2 or 3; they have an octahedral structure. The water molecules function as Lewis bases, donating a pair of electrons to the metal ion and forming a dative covalent bond ...
Aluminium oxide (or aluminium(III) oxide) is a chemical compound of aluminium and oxygen with the chemical formula Al 2 O 3. It is the most commonly occurring of several aluminium oxides, and specifically identified as aluminium oxide. It is commonly called alumina and may also be called aloxide, aloxite, or alundum in various forms and ...
The existence of a very long C–C bond length of up to 290 pm is claimed in a dimer of two tetracyanoethylene dianions, although this concerns a 2-electron-4-center bond. [4] [5] This type of bonding has also been observed in neutral phenalenyl dimers. The bond lengths of these so-called "pancake bonds" [6] are up to 305 pm.
The strong bonding of metals in liquid form demonstrates that the energy of a metallic bond is not highly dependent on the direction of the bond; this lack of bond directionality is a direct consequence of electron delocalization, and is best understood in contrast to the directional bonding of covalent bonds.
The perovskite structure is frequently found for ternary oxides formed with one large (A) and one small cation (B). In this structure, there is a simple cubic array of B cations, with the A cations occupying the center of the cube, and the oxide atoms are sited at the center of the 12 edges of the simple cube. [8] [5] [6] [7]
The presence of iron in aluminum helps in the decrease of casting defects, improves tensile, yield, hardness, and maintains strength at high temperatures. [3] The first recorded usage of the word "ferroaluminum" was in 1887. [4] [5] Ferroaluminum can also be nitrided, as the aluminium bonds well with the nitrogen forming a hard case. The ...
Reaction with Al 2 I 6 yields subvalent halide species; reaction with As 4 tBu 4 yields As-Al bonds. [6] When reacted with transition metal-cyclopentadienyl complexes such as NiCp 2, it offers a straightforward pathway to compounds containing aluminium-transition metal bonds, which has great potential for important catalytic reactions. [2]