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Energy supplied at a higher temperature (i.e. with low entropy) tends to be more useful than the same amount of energy available at a lower temperature. Mixing a hot parcel of a fluid with a cold one produces a parcel of intermediate temperature, in which the overall increase in entropy represents a "loss" that can never be replaced.
Thus, G or A is the amount of energy "free" for work under the given conditions. Up until this point, the general view had been such that: “all chemical reactions drive the system to a state of equilibrium in which the affinities of the reactions vanish”. Over the next 60 years, the term affinity came to be replaced with the term free energy.
In terms of energy flow, the movement from a magnetically aligned state requires energy from the thermal motion of the molecules, converting thermal energy into magnetic energy. [24] Yet, according to the second law of thermodynamics , because no heat can enter or leave the container, due to its adiabatic insulation, the system should exhibit ...
The term enthalpy was coined relatively late in the history of thermodynamics, in the early 20th century. Energy was introduced in a modern sense by Thomas Young in 1802, while entropy by Rudolf Clausius in 1865. Energy uses the root of the Greek word ἔργον (ergon), meaning "work", [22] to express the idea of capacity to perform work.
The concept of free energy was developed by Hermann von Helmholtz, a German physicist, and first presented in 1882 in a lecture called "On the thermodynamics of chemical processes". [1] From the German word Arbeit (work), the International Union of Pure and Applied Chemistry (IUPAC) recommends the symbol A and the name Helmholtz energy. [2]
Thomas Young, the first person to use the term "energy" in the modern sense. The word energy derives from the Ancient Greek: ἐνέργεια, romanized: energeia, lit. 'activity, operation', [4] which possibly appears for the first time in the work of Aristotle in the 4th century BC. In contrast to the modern definition, energeia was a ...
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The first law of thermodynamics is a formulation of the law of conservation of energy in the context of thermodynamic processes.The law distinguishes two principal forms of energy transfer, heat and thermodynamic work, that modify a thermodynamic system containing a constant amount of matter.