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  2. Oxygen evolution - Wikipedia

    en.wikipedia.org/wiki/Oxygen_evolution

    Oxygen evolution is the chemical process of generating elemental diatomic oxygen (O 2) by a chemical reaction, usually from water, the most abundant oxide compound in the universe. Oxygen evolution on Earth is effected by biotic oxygenic photosynthesis , photodissociation , hydroelectrolysis , and thermal decomposition of various oxides and ...

  3. Heterogeneous water oxidation - Wikipedia

    en.wikipedia.org/wiki/Heterogeneous_Water_Oxidation

    Of the two half reactions, the oxidation step is the most demanding because it requires the coupling of 4 electron and proton transfers and the formation of an oxygen-oxygen bond. This process occurs naturally in plants photosystem II to provide protons and electrons for the photosynthesis process and release oxygen to the atmosphere, [ 1 ] as ...

  4. Geological history of oxygen - Wikipedia

    en.wikipedia.org/wiki/Geological_history_of_oxygen

    Under low oxygen concentrations and before the evolution of nitrogen fixation, biologically-available nitrogen compounds were in limited supply, [16] and periodic "nitrogen crises" could render the ocean inhospitable to life. [9] Significant concentrations of oxygen were just one of the prerequisites for the evolution of complex life. [9]

  5. Water oxidation catalysis - Wikipedia

    en.wikipedia.org/wiki/Water_oxidation_catalysis

    X-ray Crystal structure of the Mn 4 O 5 Ca core of the oxygen evolving complex of Photosystem II at a resolution of 1.9 Å. [1] Water oxidation catalysis (WOC) is the acceleration (catalysis) of the conversion of water into oxygen and protons: 2 H 2 O → 4 H + + 4 e − + O 2. Many catalysts are effective, both homogeneous catalysts and ...

  6. Oxygen-evolving complex - Wikipedia

    en.wikipedia.org/wiki/Oxygen-evolving_complex

    The oxygen-evolving complex (OEC), also known as the water-splitting complex, is a water-oxidizing enzyme involved in the photo-oxidation of water during the light reactions of photosynthesis. [3] OEC is surrounded by 4 core proteins of photosystem II at the membrane-lumen interface.

  7. Artificial photosynthesis - Wikipedia

    en.wikipedia.org/wiki/Artificial_photosynthesis

    Water oxidation is a more complex chemical reaction than proton reduction. In nature, the oxygen-evolving complex performs this reaction by accumulating reducing equivalents (electrons) in a manganese-calcium cluster within photosystem II (PS II), then delivering them to water molecules, with the resulting production of molecular oxygen and ...

  8. Dioxygen in biological reactions - Wikipedia

    en.wikipedia.org/wiki/Dioxygen_in_biological...

    After being carried in blood to a body tissue in need of oxygen, O 2 is handed off from the heme group to monooxygenase, an enzyme that also has an active site with an atom of iron. [9] Monooxygenase uses oxygen for many oxidation reactions in the body. Oxygen that is suspended in the blood plasma equalizes into the tissue according to Henry's law.

  9. Neoproterozoic oxygenation event - Wikipedia

    en.wikipedia.org/wiki/Neoproterozoic_oxygenation...

    This, combined with the evolution of benthic filter feeders (e.g. choanoflagellates and primitive poriferans such as Otavia), is believed to have shifted oxygen demand further down in the water column, which would result in a positive feedback loop wherein phosphorus was removed from the ocean, which reduced productivity and decreased oxygen ...