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A pH meter is a scientific instrument that measures the hydrogen-ion activity in water-based solutions, indicating its acidity or alkalinity expressed as pH. [2] The pH meter measures the difference in electrical potential between a pH electrode and a reference electrode, and so the pH meter is sometimes referred to as a "potentiometric pH meter".
Quinones form a quinhydrone cocrystal by formation of hydrogen bonding between ρ-quinone and ρ-hydroquinone. [3] An equimolar mixture of ρ-quinones and ρ-hydroquinone in contact with an inert metallic electrode, such as antimony, forms what is known as a quinhydrone electrode. Such devices can be used to measure the pH of solutions. [4]
The key to Bjerrum's method was the use of the then recently developed glass electrode and pH meter to determine the concentration of hydrogen ions in solution. Bjerrum recognised that the formation of a metal complex with a ligand was a kind of acid–base equilibrium : there is competition for the ligand, L, between the metal ion, M n+ , and ...
The concentration of hydrogen ions and pH are inversely proportional; in an aqueous solution, an increased concentration of hydrogen ions yields a low pH, and subsequently, an acidic product. By definition, an acid is an ion or molecule that can donate a proton, and when introduced to a solution it will react with water molecules (H 2 O) to ...
Internal solution, usually a pH=7 buffered solution of 0.1 mol/L KCl for pH electrodes or 0.1 mol/L MCl for pM electrodes. When using the silver chloride electrode, a small amount of AgCl can precipitate inside the glass electrode. Reference electrode, usually the same type as 2. Reference internal solution, usually 3.0 mol/L KCl.
pH values can be measured in non-aqueous solutions, but they are based on a different scale from aqueous pH values because the standard states used for calculating hydrogen ion concentrations are different. The hydrogen ion activity, a H +, is defined [21] [22] as:
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