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[1] [2] This deviation from linearity is described as the non-linear effect, NLE. [3] The linearity can be expressed mathematically , as shown in Equation 1. Stereoselection (i.e. the ee product ) that is higher or lower than the enantiomeric excess of the catalyst (ee catalyst , relative to the equation) is considered non-routine behavior.
Example of a linear molecule. N atoms in a molecule have 3N degrees of freedom which constitute translations, rotations, and vibrations.For non-linear molecules, there are 3 degrees of freedom for translational (motion along the x, y, and z directions) and 3 degrees of freedom for rotational motion (rotations in R x, R y, and R z directions) for each atom.
In chemistry, a chemical oscillator is a complex mixture of reacting chemical compounds in which the concentration of one or more components exhibits periodic changes. They are a class of reactions that serve as an example of non-equilibrium thermodynamics with far-from-equilibrium behavior.
An example of linear motion is an athlete running a 100-meter dash along a straight track. [2] Linear motion is the most basic of all motion. According to Newton's first law of motion, objects that do not experience any net force will continue to move in a straight line with a constant velocity until they are subjected to a net force. Under ...
In chemistry and molecular physics, fluxional (or non-rigid) molecules are molecules that undergo dynamics such that some or all of their atoms interchange between symmetry-equivalent positions. [1] Because virtually all molecules are fluxional in some respects, e.g. bond rotations in most organic compounds , the term fluxional depends on the ...
Nonlinear ones are of particular interest for their commonality in describing real-world systems and how much more difficult they are to solve compared to linear differential equations. This list presents nonlinear ordinary differential equations that have been named, sorted by area of interest.
In mathematics and science, a nonlinear system (or a non-linear system) is a system in which the change of the output is not proportional to the change of the input. [1] [2] Nonlinear problems are of interest to engineers, biologists, [3] [4] [5] physicists, [6] [7] mathematicians, and many other scientists since most systems are inherently nonlinear in nature. [8]
There are two main descriptions of motion: dynamics and kinematics.Dynamics is general, since the momenta, forces and energy of the particles are taken into account. In this instance, sometimes the term dynamics refers to the differential equations that the system satisfies (e.g., Newton's second law or Euler–Lagrange equations), and sometimes to the solutions to those equations.
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