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Heat capacity or thermal capacity is a physical property of matter, defined as the amount of heat to be supplied to an object to produce a unit change in its temperature. [1] The SI unit of heat capacity is joule per kelvin (J/K). Heat capacity is an extensive property.
In addition, an oscillating system may be subject to some external force, as when an AC circuit is connected to an outside power source. In this case the oscillation is said to be driven. The simplest example of this is a spring-mass system with a sinusoidal driving force.
Theoretical models of oscillating reactions have been studied by chemists, physicists, and mathematicians. In an oscillating system the energy-releasing reaction can follow at least two different pathways, and the reaction periodically switches from one pathway to another. One of these pathways produces a specific intermediate, while another ...
For example, heat capacity is an extensive property of a system. Dividing heat capacity, , by the mass of the system gives the specific heat capacity, , which is an intensive property. When the extensive property is represented by an upper-case letter, the symbol for the corresponding intensive property is usually represented by a lower-case ...
The macroscopic energy equation for infinitesimal volume used in heat transfer analysis is [6] = +, ˙, where q is heat flux vector, −ρc p (∂T/∂t) is temporal change of internal energy (ρ is density, c p is specific heat capacity at constant pressure, T is temperature and t is time), and ˙ is the energy conversion to and from thermal ...
where C is the heat capacity, it follows that: = The heat capacity depends on how the external variables of the system are changed when the heat is supplied. If the only external variable of the system is the volume, then we can write:
Molar heat capacity of most elements at 25 °C is in the range between 2.8 R and 3.4 R: Plot as a function of atomic number with a y range from 22.5 to 30 J/mol K.. The Dulong–Petit law, a thermodynamic law proposed by French physicists Pierre Louis Dulong and Alexis Thérèse Petit, states that the classical expression for the molar specific heat capacity of certain chemical elements is ...
Every degree of freedom in the energy is quadratic and, thus, should contribute 1 ⁄ 2 k B T to the total average energy, and 1 ⁄ 2 k B to the heat capacity. Therefore, the heat capacity of a gas of N diatomic molecules is predicted to be 7N· 1 ⁄ 2 k B: the momenta p 1 and p 2 contribute three degrees of freedom each, and the extension q ...