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Most computerized databases will create a table of thermodynamic values using the values from the datafile. For MgCl 2 (c,l,g) at 1 atm pressure: Thermodynamic properties table for MgCl 2 (c,l,g), from the FREED datafile. Some values have truncated significant figures for display purposes. The table format is a common way to display ...
For many substances, the formation reaction may be considered as the sum of a number of simpler reactions, either real or fictitious. The enthalpy of reaction can then be analyzed by applying Hess' law, which states that the sum of the enthalpy changes for a number of individual reaction steps equals the enthalpy change of the overall reaction.
The enthalpy of formation of one mole of ethane gas refers to the reaction 2 C (graphite) + 3 H 2 (g) → C 2 H 6 (g). Standard enthalpy of hydrogenation is defined as the enthalpy change observed when one mole of an unsaturated compound reacts with an excess of hydrogen to become fully
The standard Gibbs free energy of formation (G f °) of a compound is the change of Gibbs free energy that accompanies the formation of 1 mole of a substance in its standard state from its constituent elements in their standard states (the most stable form of the element at 1 bar of pressure and the specified temperature, usually 298.15 K or 25 °C).
In part because of its high polarity, HCl is very soluble in water (and in other polar solvents). Upon contact, H 2 O and HCl combine to form hydronium cations [H 3 O] + and chloride anions Cl − through a reversible chemical reaction: HCl + H 2 O → [H 3 O] + + Cl −. The resulting solution is called hydrochloric acid and is a strong acid.
Std enthalpy of formation Δ f H o solid: −408.27 kJ/mol Standard molar entropy S o solid: 59.33 J/(mol K) Heat capacity c p: 47.99 J/(mol K) Liquid properties Std enthalpy of formation Δ f H o liquid: −390.76 kJ/mol Standard molar entropy S o liquid? J/(mol K) Heat capacity c p? J/(mol K) Gas properties Std enthalpy of formation Δ f H o ...
Std enthalpy change of formation, Δ f H o liquid –169.7 kJ/mol Standard molar entropy, S o liquid: 208.53 J/(mol K) Enthalpy of combustion, Δ c H o liquid –1236.4 kJ/mol Heat capacity, c p: 129.0 J/(mol K) Gas properties Std enthalpy change of formation, Δ f H o gas –125.4 kJ/mol Standard molar entropy, S o gas? J/(mol K) Heat capacity ...
J.A. Dean (ed), Lange's Handbook of Chemistry (15th Edition), McGraw-Hill, 1999; Section 6, Thermodynamic Properties; Table 6.4, Heats of Fusion, Vaporization, and Sublimation and Specific Heat at Various Temperatures of the Elements and Inorganic Compounds