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Carbonatation is a slow process that occurs in concrete where lime (CaO, or Ca(OH) 2 ) in the cement reacts with carbon dioxide (CO 2) from the air and forms calcium carbonate. The water in the pores of Portland cement concrete is normally alkaline with a pH in the range of 12.5 to 13.5.
Concrete carbonation can be visually revealed by applying a phenolphthalein solution over the fresh surface of a concrete samples (concrete core, prism, freshly fractured bar). Phenolphthalein is a pH indicator , whose color turns from colorless at pH < 8.5 to pink-fuchsia at pH > 9.5.
Concrete is a composite material composed of aggregate bonded together with a fluid cement that cures to a solid over time. Concrete is the second-most-used substance in the world after water, [1] and is the most widely used building material. [2] Its usage worldwide, ton for ton, is twice that of steel, wood, plastics, and aluminium combined. [3]
Carbonation process is considered as a mechanism of concrete degradation. It reduces pH of concrete that promotes reinforcement steel corrosion. [72] However, as the product of Ca(OH)2 carbonation, CaCO3, occupies a greater volume, porosity of concrete reduces. This increases strength and hardness of concrete. [75]
The speed of carbonation depends primarily on the porosity of the concrete and its moisture content. Carbonation in concrete pores happens only at a relative humidity (RH) of 40-90%—when RH is higher than 90%, carbon dioxide cannot enter the concrete pores, and when RH is lower than 40%, CO 2 cannot be dissolved in water. [28]
As the sulfate form is the dominant one in AFm phases in the hardened cement paste (HCP) in concrete, AFm is often simply referred to as Aluminate Ferrite monosulfate or calcium aluminate monosulfate. However, carbonate-AFm phases also exist (monocarbonate and hemicarbonate) and are thermodynamically more stable than the sulfate-AFm phase.
Calcium carbonate (CaCO 3), often known as limestone, has an effective bonding capability and is compatible with current concrete formulations. As a result of the carbonation of existing calcium hydroxide (portlandite) minerals, calcium carbonate may be included in the concrete mix design or chemically created inside the concrete matrix.
The calcium carbonate heals the concrete by solidifying on the cracked concrete surface, mimicking the process by which bone fractures in human body are healed by osteoblast cells that mineralize to reform the bone. [36] Two methods are currently being studied: injection of calcium carbonate precipitating bacteria.
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