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In chemistry the polyhedral skeletal electron pair theory (PSEPT) provides electron counting rules useful for predicting the structures of clusters such as borane and carborane clusters. The electron counting rules were originally formulated by Kenneth Wade , [ 1 ] and were further developed by others including Michael Mingos ; [ 2 ] they are ...
The geometry and bonding of a Zintl ion cannot be easily described by classical two electron two center bonding theories; however the geometries Zintl ions can be well described by Wade’s rules of boranes. Wade’s rules offer an alternative model for the relationship between geometry and electron count in delocalized electron deficient ...
In chemistry, the Jemmis mno rules represent a unified rule for predicting and systematizing structures of compounds, usually clusters.The rules involve electron counting. They were formulated by E. D. Jemmis to explain the structures of condensed polyhedral boranes such as B 20 H 16, which are obtained by condensing polyhedral boranes by sharing a triangular face, an edge, a single vertex, or ...
A mnemonic is a memory aid used to improve long-term memory and make the process of consolidation easier. Many chemistry aspects, rules, names of compounds, sequences of elements, their reactivity, etc., can be easily and efficiently memorized with the help of mnemonics.
In organometallic chemistry, the Green–Davies–Mingos rules predict the regiochemistry for nucleophilic addition to 18-electron metal complexes containing multiple unsaturated ligands. [1] The rules were published in 1978 by organometallic chemists Stephen G. Davies , Malcolm Green , and Michael Mingos .
According to Wade's rules (2n+2) the number of cluster electrons is 22 and therefore a closo cluster. The compound is prepared from oxidation of K 4 Pb 9 [ 15 ] by Au + in PPh 3 AuCl (by reaction of tetrachloroauric acid and triphenylphosphine ) in ethylene diamine with 2.2.2-crypt .
In chemistry, the lever rule is a formula used to determine the mole fraction (x i) or the mass fraction (w i) of each phase of a binary equilibrium phase diagram. It can be used to determine the fraction of liquid and solid phases for a given binary composition and temperature that is between the liquidus and solidus line. [1]
Inorganic compounds exhibit a range of bonding properties. Some are ionic compounds, consisting of very simple cations and anions joined by ionic bonding.Examples of salts (which are ionic compounds) are magnesium chloride MgCl 2, which consists of magnesium cations Mg 2+ and chloride anions Cl −; or sodium hydroxide NaOH, which consists of sodium cations Na + and hydroxide anions OH −.