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On the other hand, when a granular material starts in a very loose state it may continuously compact instead of dilating under shear. A sample of a material is called dilative if its volume increases with increasing shear and contractive if the volume decreases with increasing shear. [7] [8] Dilatancy is a common feature of soils and sands. Its ...
The Seyferth–Gilbert homologation is a chemical reaction of an aryl ketone 1 (or aldehyde) with dimethyl (diazomethyl)phosphonate 2 and potassium tert-butoxide to give substituted alkynes 3. [ 1 ] [ 2 ] Dimethyl (diazomethyl)phosphonate 2 is often called the Seyferth–Gilbert reagent .
Plot of shear rate as a function of the shear stress. Dilatants in green. A dilatant (/ d aɪ ˈ l eɪ t ə n t /, / d ɪ-/) (also termed shear thickening [1]) material is one in which viscosity increases with the rate of shear strain. Such a shear thickening fluid, also known by the initialism STF, is an example of a non-Newtonian fluid.
The overall chemical reaction taking place in a cell is made up of two independent half-reactions, which describe chemical changes at the two electrodes. To focus on the reaction at the working electrode, the reference electrode is standardized with constant (buffered or saturated) concentrations of each participant of the redox reaction. [1]
A high-shear mixer disperses, or transports, one phase or ingredient (liquid, solid, gas) into a main continuous phase (liquid), with which it would normally be immiscible. A rotor or impeller, together with a stationary component known as a stator, or an array of rotors and stators, is used either in a tank containing the solution to be mixed ...
For the simple shear case, it is just a gradient of velocity in a flowing material. The SI unit of measurement for shear rate is s −1, expressed as "reciprocal seconds" or "inverse seconds". [1] However, when modelling fluids in 3D, it is common to consider a scalar value for the shear rate by calculating the second invariant of the strain ...
The anion [Ce(NO 3) 6] 2− has T h (idealized O h) molecular symmetry. The CeO 12 core defines an icosahedron. [4] Ce 4+ is a strong one-electron oxidizing agent. In terms of its redox potential (E° ≈ 1.61 V vs. N.H.E.) it is an even stronger oxidizing agent than Cl 2 (E° ≈ 1.36 V). Few shelf-stable reagents are stronger oxidants.
The CRC Handbook of Chemistry and Physics is a comprehensive one-volume reference resource for science research. First published in 1914, it is currently (as of 2024) in its 105th edition, published in 2024. It is known colloquially among chemists as the "Rubber Bible", as CRC originally stood for "Chemical Rubber Company". [2]