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In thermodynamics, the Joule–Thomson effect (also known as the Joule–Kelvin effect or Kelvin–Joule effect) describes the temperature change of a real gas or liquid (as differentiated from an ideal gas) when it is expanding; typically caused by the pressure loss from flow through a valve or porous plug while keeping it insulated so that no heat is exchanged with the environment.
This temperature change is known as the Joule–Thomson effect, and is exploited in the liquefaction of gases. Inversion temperature depends on the nature of the gas. For a van der Waals gas we can calculate the enthalpy using statistical mechanics as
The Joule expansion (a subset of free expansion) is an irreversible process in thermodynamics in which a volume of gas is kept in one side of a thermally isolated container (via a small partition), with the other side of the container being evacuated. The partition between the two parts of the container is then opened, and the gas fills the ...
The Joule effect (during Joule expansion), the temperature change of a gas (usually cooling) when it is allowed to expand freely. The Joule–Thomson effect , the temperature change of a gas when it is forced through a valve or porous plug while keeping it insulated so that no heat is exchanged with the environment.
An expansion tank or expansion vessel is a small tank used to protect closed water heating systems and domestic hot water systems from excessive pressure. The tank is partially filled with air, whose compressibility cushions shock caused by water hammer [ citation needed ] and absorbs excess water pressure caused by thermal expansion .
The Hampson–Linde cycle differs from the Siemens cycle only in the expansion step. Whereas the Siemens cycle has the gas do external work to reduce its temperature, the Hampson–Linde cycle relies solely on the Joule–Thomson effect; this has the advantage that the cold side of the cooling apparatus needs no moving parts. [1]
The Thomson effect is an extension of the Peltier–Seebeck model and is credited to Lord Kelvin. Joule heating, the heat that is generated whenever a current is passed through a conductive material, is not generally termed a thermoelectric effect.
Note that the especially high molar values, as for paraffin, gasoline, water and ammonia, result from calculating specific heats in terms of moles of molecules. If specific heat is expressed per mole of atoms for these substances, none of the constant-volume values exceed, to any large extent, the theoretical Dulong–Petit limit of 25 J⋅mol ...
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