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Pauling's second rule is that the value of the first pK a for acids of the formula XO m (OH) n depends primarily on the number of oxo groups m, and is approximately independent of the number of hydroxy groups n, and also of the central atom X. Approximate values of pK a are 8 for m = 0, 2 for m = 1, −3 for m = 2 and < −10 for m = 3. [28]
The absorption rate constant K a is a value used in pharmacokinetics to describe the rate at which a drug enters into the system. It is expressed in units of time −1. [1] The K a is related to the absorption half-life (t 1/2a) per the following equation: K a = ln(2) / t 1/2a. [1] K a values can typically only be found in research articles. [2]
In chemistry, biochemistry, and pharmacology, a dissociation constant (K D) is a specific type of equilibrium constant that measures the propensity of a larger object to separate (dissociate) reversibly into smaller components, as when a complex falls apart into its component molecules, or when a salt splits up into its component ions.
Such plots have been also used to calibrate glass electrodes, to estimate the carbonate content of aqueous solutions, and to estimate the K a values (acid dissociation constants) of weak acids and bases from titration data. Gran plots are named after Swedish chemist Gunnar Gran, who developed the method in 1950. [1]
For instance, hydrogen fluoride, whether dissolved in water (= 3.2) or DMSO (= 15), has values indicating that it undergoes incomplete dissociation in these solvents, making it a weak acid. However, as the rigorously dried, neat acidic medium, hydrogen fluoride has an H 0 {\displaystyle H_{0}} value of –15, [ 1 ] making it a more strongly ...
1.191 042 972... × 10 −16 W⋅m 2 ⋅sr −1: 0 [11] = / second radiation constant: 1.438 776 877... × 10 −2 m⋅K: 0 [12] [e] Wien wavelength displacement law constant: 2.897 771 955... × 10 −3 m⋅K: 0 [13] ′ [f] Wien frequency displacement law constant: 5.878 925 757... × 10 10 Hz⋅K −1: 0
In chemistry, acid value (AV, acid number, neutralization number or acidity) is a number used to quantify the acidity of a given chemical substance. It is the quantity of base (usually potassium hydroxide (KOH)), expressed as milligrams of KOH required to neutralize the acidic constituents in 1 gram of a sample.
A weak acid may be defined as an acid with pK a greater than about −2. An acid with pK a = −2 would be 99 % dissociated at pH 0, that is, in a 1 M HCl solution. Any acid with a pK a less than about −2 is said to be a strong acid. Strong acids are said to be fully dissociated.
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