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Transition state theory explains the dynamics of reactions. The theory is based on the idea that there is an equilibrium between the activated complex and reactant molecules. The theory incorporates concepts from collision theory, which states that for a reaction to occur, reacting molecules must collide with a minimum energy and correct ...
The equation follows from the transition state theory, also known as activated-complex theory. If one assumes a constant enthalpy of activation and constant entropy of activation, the Eyring equation is similar to the empirical Arrhenius equation , despite the Arrhenius equation being empirical and the Eyring equation based on statistical ...
This theory was developed simultaneously in 1935 by Henry Eyring, then at Princeton University, and by Meredith Gwynne Evans and Michael Polanyi of the University of Manchester. [3] [4] [5] TST is also referred to as "activated-complex theory", "absolute-rate theory", and "theory of absolute reaction rates". [6]
Complexity theory emphasizes interactions and the accompanying feedback loops that constantly change systems. While it proposes that systems are unpredictable, they are also constrained by order-generating rules. [6]: 74 Complexity theory has been used in the fields of strategic management and organizational studies.
Complexity science is not a single theory—it encompasses more than one theoretical framework and is interdisciplinary, seeking the answers to some fundamental questions about living, adaptable, changeable systems. Complex adaptive systems may adopt hard or softer approaches. [8]
A chain reaction is an example of a complex mechanism, in which the propagation steps form a closed cycle. In a chain reaction, the intermediate produced in one step generates an intermediate in another step. Intermediates are called chain carriers. Sometimes, the chain carriers are radicals, they can be ions as well.
The process of chemical reaction can be considered as involving the diffusion of reactants until they encounter each other in the right stoichiometry and form an activated complex which can form the product species. The observed rate of chemical reactions is, generally speaking, the rate of the slowest or "rate determining" step.
The activation theory describes how we are physiologically aroused and how that affects our functioning. The evaluation theory relates to the systematic assessment of the worth or merit of some object. The attention theory takes into account possession in the mind including focalization and concentration of consciousness.