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Detonation (from Latin detonare 'to thunder down/forth') [1] is a type of combustion involving a supersonic exothermic front accelerating through a medium that eventually drives a shock front propagating directly in front of it.
In spark-ignition internal combustion engines, knocking (also knock, detonation, spark knock, pinging or pinking) occurs when combustion of some of the air/fuel mixture in the cylinder does not result from propagation of the flame front ignited by the spark plug, but when one or more pockets of air/fuel mixture explode outside the envelope of the normal combustion front.
It states that the detonation propagates at a velocity at which the reacting gases just reach sonic velocity (in the frame of the leading shock wave) as the reaction ceases. [1] [2] David Chapman [3] and Émile Jouguet [4] originally (c. 1900) stated the condition for an infinitesimally thin detonation.
A schematic diagram of a shock wave situation with the density , velocity , and temperature indicated for each region.. The Rankine–Hugoniot conditions, also referred to as Rankine–Hugoniot jump conditions or Rankine–Hugoniot relations, describe the relationship between the states on both sides of a shock wave or a combustion wave (deflagration or detonation) in a one-dimensional flow in ...
The duration of the blast wave depends on the type of explosive material and the distance from the point of detonation. The blast wave progresses from the source of explosion as a sphere of compressed and rapidly expanding gases, which displaces an equal volume of air at a very high velocity. The velocity of the blast wave in air may be ...
The phenomenon is exploited in pulse detonation engines, because a detonation produces a more efficient combustion of the reactants than a deflagration does, i.e. giving a higher yields. Such engines typically employ a Shchelkin spiral in the combustion chamber to facilitate the deflagration to detonation transition. [2] [3]
Typical detonation velocities for organic dust mixtures range from 1400 to 1650 m/s. [2] Gas explosions can either deflagrate or detonate based on confinement; detonation velocities are generally around 1700 m/s [3] [4] [5] but can be as high as 3000 m/s. [6] Solid explosives often have detonation velocities ranging beyond 4000 m/s to 10300 m/s.
RDX undergoes a deflagration to detonation transition (DDT) in confinement and certain circumstances. [73] The velocity of detonation of RDX at a density of 1.80 g/cm 3 is 8750 m/s. [74] [page needed] It starts to decompose at approximately 170 °C and melts at 204 °C. At room temperature, it is very stable. It burns rather than explodes.