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A macroscopic quantum state is a state of matter in which macroscopic properties, such as mechanical motion, [1] thermal conductivity, electrical conductivity [2] and viscosity, can be described only by quantum mechanics rather than merely classical mechanics. [3]
At temperatures below the lambda point, helium shows the unique property of superfluidity. The fraction of the liquid that forms the superfluid component is a macroscopic quantum fluid. The helium atom is a neutral particle, so q = 0. Furthermore, when considering helium-4, the relevant particle mass is m = m 4, so Eq. reduces to
The macroscopic scale is the length scale on which objects or phenomena are large enough to be visible with the naked eye, without magnifying optical instruments. [ 1 ] [ 2 ] It is the opposite of microscopic .
Classical thermodynamics is the description of the states of thermodynamic systems at near-equilibrium, that uses macroscopic, measurable properties. It is used to model exchanges of energy, work and heat based on the laws of thermodynamics.
Physical chemistry is the study of macroscopic and microscopic phenomena in chemical systems in terms of the principles, practices, and concepts of physics such as motion, energy, force, time, thermodynamics, quantum chemistry, statistical mechanics, analytical dynamics and chemical equilibria.
Boyle also believed that all macroscopic properties, including color, taste and elasticity, are caused by and ultimately consist of nothing but the arrangement and motion of indivisible particles of matter. [9] In a lecture of 1681, Hooke asserted a direct relationship between the temperature of an object and the speed of its internal particles.
Statistical mechanics arose out of the development of classical thermodynamics, a field for which it was successful in explaining macroscopic physical properties—such as temperature, pressure, and heat capacity—in terms of microscopic parameters that fluctuate about average values and are characterized by probability distributions.
The microscopic version was introduced by Lorentz, who tried to use it to derive the macroscopic properties of bulk matter from its microscopic constituents. [12]: 5 "Maxwell's macroscopic equations", also known as Maxwell's equations in matter, are more similar to those that Maxwell introduced himself.