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Chromium trioxide is mainly used in chrome plating. It is typically employed with additives that affect the plating process but do not react with the trioxide. The trioxide reacts with cadmium, zinc, and other metals to generate passivating chromate films that resist corrosion. It is also used in the production of synthetic rubies.
Jones reagent is a solution prepared by dissolving chromium trioxide in aqueous sulfuric acid. To effect a Jones oxidation, this acidic mixture is then added to an acetone solution of the substrate. Alternatively, potassium dichromate can be used in place of chromium trioxide.
Because of its considerable stability, chromia is a commonly used pigment. It was originally called viridian. It is used in paints, inks, and glasses. It is the colorant in "chrome green" and "institutional green." Chromium(III) oxide is a precursor to the magnetic pigment chromium dioxide, by the following reaction: [8] Cr 2 O 3 + 3 CrO 3 → ...
Hexavalent chromium compounds (including chromium trioxide, chromic acids, chromates, chlorochromates) are toxic and carcinogenic. Chromium trioxide and chromic acids are strong oxidizers and may react violently if mixed with easily oxidizable organic substances. Chromic acid burns are treated with a dilute sodium thiosulfate solution. [18]
The complex is produced by treating chromium trioxide with pyridine. [2] The complex is diamagnetic. According to X-ray crystallography, the complex is 5-coordinate with mutually trans pyridine ligands. The Cr-O and Cr-N distances are respectively 163 and 215 picometers. [3] In terms of history, the complex was first produced by Sisler et al. [4]
Image credits: Sasha Weilbaker #7 Solar Panels. While both solar panels and plant leaves harvest energy from the sun, a team at Princeton University took biomimicry in solar panels a step further ...
The Sarett oxidation is an organic reaction that oxidizes primary and secondary alcohols to aldehydes and ketones, respectively, using chromium trioxide and pyridine.Unlike the similar Jones oxidation, the Sarett oxidation will not further oxidize primary alcohols to their carboxylic acid form, neither will it affect carbon-carbon double bonds. [1]
A large number of chromium(III) compounds are known, such as chromium(III) nitrate, chromium(III) acetate, and chromium(III) oxide. [33] Chromium(III) can be obtained by dissolving elemental chromium in acids like hydrochloric acid or sulfuric acid , but it can also be formed through the reduction of chromium(VI) by cytochrome c7 . [ 34 ]
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