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Atomic orbitals are basic building blocks of the atomic orbital model (or electron cloud or wave mechanics model), a modern framework for visualizing submicroscopic behavior of electrons in matter. In this model, the electron cloud of an atom may be seen as being built up (in approximation) in an electron configuration that is a product of ...
The Bohr model of the hydrogen atom (Z = 1) or a hydrogen-like ion (Z > 1), where the negatively charged electron confined to an atomic shell encircles a small, positively charged atomic nucleus and where an electron jumps between orbits, is accompanied by an emitted or absorbed amount of electromagnetic energy (hν). [1]
In the end, the model was replaced by the modern quantum-mechanical treatment of the hydrogen atom, which was first given by Wolfgang Pauli in 1925, using Heisenberg's matrix mechanics. The current picture of the hydrogen atom is based on the atomic orbitals of wave mechanics, which Erwin Schrödinger developed in 1926.
The Bohr model of the atom, with an electron making instantaneous "quantum leaps" from one orbit to another with gain or loss of energy. This model of electrons in orbits is obsolete. A problem in classical mechanics is that an accelerating charged particle radiates electromagnetic radiation, causing the particle to lose kinetic energy.
[44]: 1 [45] Schrödinger computed the hydrogen spectral series by treating a hydrogen atom's electron as a wave (,), moving in a potential well, created by the proton. This computation accurately reproduced the energy levels of the Bohr model .
For example, the electron wave function for an unexcited hydrogen atom is a spherically symmetric function known as an s orbital . Analytic solutions of the Schrödinger equation are known for very few relatively simple model Hamiltonians including the quantum harmonic oscillator , the particle in a box , the dihydrogen cation , and the ...
Wave-particle duality is the concept in quantum mechanics that quantum entities exhibit particle or wave properties according to the experimental circumstances. [ 1 ] : 59 It expresses the inability of the classical concepts such as particle or wave to fully describe the behavior of quantum objects. [ 2 ] :
The pilot-wave model and interpretation was then abandoned, in favor of the quantum formalism, until 1952 when it was rediscovered and enhanced by David Bohm. [ 9 ] Louis de Broglie was the sixteenth member elected to occupy seat 1 of the Académie française in 1944, and served as Perpetual Secretary of the French Academy of Sciences .