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Specific volume is the volume occupied by a unit of mass of a material. [1] In many cases, the specific volume is a useful quantity to determine because, as an intensive property, it can be used to determine the complete state of a system in conjunction with another independent intensive variable. The specific volume also allows systems to be ...
For quasi-static and reversible processes, the first law of thermodynamics is: d U = δ Q − δ W {\displaystyle dU=\delta Q-\delta W} where δQ is the heat supplied to the system and δW is the work done by the system.
The behavior of a thermodynamic system is summarized in the laws of Thermodynamics, which concisely are: . Zeroth law of thermodynamics; If A, B, C are thermodynamic systems such that A is in thermal equilibrium with B and B is in thermal equilibrium with C, then A is in thermal equilibrium with C.
2 volumes of hydrogen + 1 volume of oxygen = 2 volume of gaseous water. could also be expressed as 2 molecules of hydrogen + 1 molecule of oxygen = 2 molecule of water. The law of combining volumes of gases was announced publicly by Joseph Louis Gay-Lussac on the last day of 1808, and published in 1809.
In thermodynamics, Bridgman's thermodynamic equations are a basic set of thermodynamic equations, derived using a method of generating multiple thermodynamic identities involving a number of thermodynamic quantities.
Heat capacity (constant volume) C v: J/K Specific heat capacity (constant volume) c v: J/(kg·K) Helmholtz free energy: A, F: J Helmholtz free entropy: Φ: J/K Internal energy: U: J Specific internal energy: u: J/kg Internal pressure: π T: Pa Mass: m: kg Particle number: N i – Chemical potential μ i: Pressure: p: Pa Volume V: Temperature: T ...
Specific volume is commonly applied to: Molar volume; Volume (thermodynamics) Partial molar volume; Imagine a variable-volume, airtight chamber containing a certain number of atoms of oxygen gas. Consider the following four examples: If the chamber is made smaller without allowing gas in or out, the density increases and the specific volume ...
The definition of the Gibbs function is = + where H is the enthalpy defined by: = +. Taking differentials of each definition to find dH and dG, then using the fundamental thermodynamic relation (always true for reversible or irreversible processes): = where S is the entropy, V is volume, (minus sign due to reversibility, in which dU = 0: work other than pressure-volume may be done and is equal ...