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Hematite (/ ˈ h iː m ə ˌ t aɪ t, ˈ h ɛ m ə-/), also spelled as haematite, is a common iron oxide compound with the formula, Fe 2 O 3 and is widely found in rocks and soils. [6] Hematite crystals belong to the rhombohedral lattice system which is designated the alpha polymorph of Fe 2 O 3. It has the same crystal structure as corundum ...
The ratio of Fe 2+ to Fe 3+ within a rock determines, in part, the silicate mineral and oxide mineral assemblage of the rock. Within a rock of a given chemical composition, iron enters minerals based on the bulk chemical composition and the mineral phases which are stable at that temperature and pressure.
Some examples of minerals in iron-rich rocks containing oxides are limonite, hematite, and magnetite. An example of a mineral in iron-rich rock containing carbonates is siderite and an example of minerals in an iron-rich rock containing silicate is chamosite. [2] They are often interbedded with limestones, shales, and fine-grained sandstones.
Magnetite has been important in understanding the conditions under which rocks form. Magnetite reacts with oxygen to produce hematite, and the mineral pair forms a buffer that can control how oxidizing its environment is (the oxygen fugacity). This buffer is known as the hematite-magnetite or HM buffer.
Ironstone (sandstone with iron oxides) from the Mississippian Breathitt Formation, Mile Marker 166, I-64, Kentucky. Ironstone is a sedimentary rock, either deposited directly as a ferruginous sediment or created by chemical replacement, that contains a substantial proportion of an iron ore compound from which iron (Fe) can be smelted commercially.
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The formation of hematitic jasperoids is considered to be the product of highly oxidised metasomatism of the wall rocks to a shear zone. The presence of carbonate alteration, talc-carbonated high-magnesian basalts and ultramafic rocks and the remnant mineralogy being restricted to hematite, silica, and sulfides indicates oxidising fluid chemistry.
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