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An important synthetic application using such dialkylboranes, such as diethylborane, is the transmetallation of the organoboron compounds to form organozinc compounds. [9] [10] Some diaryl and dialkylboranes are well known. Dimesitylborane is a dimer (C 6 H 2 Me 3) 4 B 2 H 2). It reacts only slowly with simple terminal alkenes.
This can be done either directly (i.e. by increasing the RAFT agent concentration) or by decreasing the rate of decomposition of or concentration of initiator. Figure 4. Major product of a RAFT polymerization (left) and other byproducts, arranged in order of decreasing prevalence.
Applications [ edit ] The tetrapropylboranuide anion is a reagent for the propylation of organometallic compounds, including organotin , organomercury , and organolead compounds of interest to environmental and public health research. [ 4 ]
Borate ions occur, alone or with other anions, in many borate and borosilicate minerals such as borax, boracite, ulexite (boronatrocalcite) and colemanite. Borates also occur in seawater, where they make an important contribution to the absorption of low frequency sound in seawater. [1] Borates also occur in plants, including almost all fruits. [2]
Many sodium borates have important industrial and household applications; the best known being borax, (Na +) 2 [B 4 O 5 (OH) 4] 2− ·8H 2 O = Na 2 B 4 H 20 O 17. The ternary phase diagram of the Na 2 O – B 2 O 3 – H 2 O phase diagram in the 0–100 °C temperature range contains 13 unique hydrated crystalline sodium borates, including ...
Before the 1990s, tetrafluoroborate, hexafluorophosphate, and perchlorate were considered weakly coordinating anions. Only by exclusion of conventional solvents were transition metal perchlorate complexes found to exist, for example.
The borate oxalates are chemical compounds containing borate and oxalate anions. Where the oxalate group is bound to the borate via oxygen, ...
Trimethyl borate is the organoboron compound with the formula B(OCH 3) 3 and a metal alkoxide. It is a colourless liquid that burns with a green flame. [1] It is an intermediate in the preparation of sodium borohydride and is a popular reagent in organic chemistry. It is a weak Lewis acid (AN = 23, Gutmann-Beckett method). [2]