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Thermal emittance or thermal emissivity is the ratio of the radiant emittance of heat of a specific object or surface to that of a standard black body.Emissivity and emittivity are both dimensionless quantities given in the range of 0 to 1, representing the comparative/relative emittance with respect to a blackbody operating in similar conditions, but emissivity refers to a material property ...
Black soot absorbs thermal radiation very well; it has an emissivity as large as 0.97, and hence soot is a fair approximation to an ideal black body. [21] [22] With the exception of bare, polished metals, the appearance of a surface to the eye is not a good guide to emissivities near room temperature.
J.A. Dean (ed), Lange's Handbook of Chemistry (15th Edition), McGraw-Hill, 1999; Section 6, Thermodynamic Properties; Table 6.3, Enthalpies and Gibbs Energies of Formation, Entropies, and Heat Capacities of the Elements and Inorganic Compounds
As quoted from this source in an online version of: J.A. Dean (ed), Lange's Handbook of Chemistry (15th Edition), McGraw-Hill, 1999; Section 4; Table 4.1, Electronic Configuration and Properties of the Elements Touloukian, Y. S., Thermophysical Properties of Matter, Vol. 12, Thermal Expansion, Plenum, New York, 1975.
However, good approximations can be made for gases in many states using simpler methods outlined below. For many solids composed of relatively heavy atoms (atomic number > iron), at non-cryogenic temperatures, the heat capacity at room temperature approaches 3R = 24.94 joules per kelvin per mole of atoms (Dulong–Petit law, R is the gas constant).
As quoted from various sources in an online version of: David R. Lide (ed), CRC Handbook of Chemistry and Physics, 84th Edition.CRC Press. Boca Raton, Florida, 2003; Section 12, Properties of Solids; Thermal and Physical Properties of Pure Metals / Thermal Conductivity of Crystalline Dielectrics / Thermal Conductivity of Metals and Semiconductors as a Function of Temperature
Kirchhoff's law of thermal radiation has a refinement in that not only is thermal emissivity equal to absorptivity, it is equal in detail. Consider a leaf. It is a poor absorber of green light (around 470 nm), which is why it looks green. By the principle of detailed balance, it is also a poor emitter of green light.
A direct practical application of the heat equation, in conjunction with Fourier theory, in spherical coordinates, is the prediction of thermal transfer profiles and the measurement of the thermal diffusivity in polymers (Unsworth and Duarte). This dual theoretical-experimental method is applicable to rubber, various other polymeric materials ...