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Lithium chloride is a chemical compound with the formula Li Cl.The salt is a typical ionic compound (with certain covalent characteristics), although the small size of the Li + ion gives rise to properties not seen for other alkali metal chlorides, such as extraordinary solubility in polar solvents (83.05 g/100 mL of water at 20 °C) and its hygroscopic properties.
Solubility of LiCl in various solvents (g LiCl / 100g of solvent at 25 °C) H 2 O: 84.5 Liquid ammonia: 3.02 Liquid sulfur dioxide: 0.012 Methanol: 21 - 41 Formic acid: 27.5 Sulfolane: 1.5 Acetonitrile: 0.14 Acetone: 0.83 Formamide: 28.2 Dimethylformamide: 11 - 28 Reference: Burgess, J. Metal Ions in Solution (Ellis Horwood, New York, 1978 ...
The following chart shows the solubility of various ionic compounds in water at 1 atm pressure and room temperature (approx. 25 °C, 298.15 K). "Soluble" means the ionic compound doesn't precipitate, while "slightly soluble" and "insoluble" mean that a solid will precipitate; "slightly soluble" compounds like calcium sulfate may require heat to precipitate.
The tables below provides information on the variation of solubility of different substances (mostly inorganic compounds) in water with temperature, at one atmosphere pressure.
A metal ion in aqueous solution or aqua ion is a cation, dissolved in water, of chemical formula [M(H 2 O) n] z+.The solvation number, n, determined by a variety of experimental methods is 4 for Li + and Be 2+ and 6 for most elements in periods 3 and 4 of the periodic table.
An aqueous solution is a solution in which the solvent is water. It is mostly shown in chemical equations by appending (aq) to the relevant chemical formula . For example, a solution of table salt , also known as sodium chloride (NaCl), in water would be represented as Na + (aq) + Cl − (aq) .
Lithium fluoride is an inorganic compound with the chemical formula LiF. It is a colorless solid that transitions to white with decreasing crystal size. Its structure is analogous to that of sodium chloride, but it is much less soluble in water. It is mainly used as a component of molten salts. [4]
Such solutions are employed in Diels–Alder reactions, where it is proposed that the Lewis acidic Li + binds to Lewis basic sites on the dienophile, thereby accelerating the reaction. [8] Lithium perchlorate is also used as a co-catalyst in the coupling of α,β-unsaturated carbonyls with aldehydes, also known as the Baylis–Hillman reaction. [9]