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All reversible heat engines between two heat reservoirs are equally efficient with a Carnot engine operating between the same reservoirs. In his ideal model, the heat of caloric converted into work could be reinstated by reversing the motion of the cycle, a concept subsequently known as thermodynamic reversibility. Carnot, however, further ...
This is an accepted version of this page This is the latest accepted revision, reviewed on 24 February 2025. Law of physics and chemistry This article is about the law of conservation of energy in physics. For sustainable energy resources, see Energy conservation. Part of a series on Continuum mechanics J = − D d φ d x {\displaystyle J=-D{\frac {d\varphi }{dx}}} Fick's laws of diffusion ...
The flow of heat is a form of energy transfer. Heat transfer is the natural process of moving energy to or from a system, other than by work or the transfer of matter. In a diathermal system, the internal energy can only be changed by the transfer of energy as heat: =.
The fact that energy can be neither created nor destroyed is called the law of conservation of energy. In the form of the first law of thermodynamics, this states that a closed system's energy is constant unless energy is transferred in or out as work or heat, and that no energy is lost in transfer. The total inflow of energy into a system must ...
The molar heat capacity is the heat capacity per unit amount (SI unit: mole) of a pure substance, and the specific heat capacity, often called simply specific heat, is the heat capacity per unit mass of a material. Heat capacity is a physical property of a substance, which means that it depends on the state and properties of the substance under ...
A respected modern author states the first law of thermodynamics as "Heat is a form of energy", which explicitly mentions neither internal energy nor adiabatic work. Heat is defined as energy transferred by thermal contact with a reservoir, which has a temperature, and is generally so large that addition and removal of heat do not alter its ...
A process without transfer of heat to or from a system, so that Q = 0, is called adiabatic, and such a system is said to be adiabatically isolated. [5] [6] The simplifying assumption frequently made is that a process is adiabatic. For example, the compression of a gas within a cylinder of an engine is assumed to occur so rapidly that on the ...
A closed system may exchange heat, experience forces, and exert forces, but does not exchange matter. An open system can interact with its surroundings by exchanging both matter and energy. The physical condition of a thermodynamic system at a given time is described by its state , which can be specified by the values of a set of thermodynamic ...