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The Nicholas reaction is an organic reaction where a dicobalt octacarbonyl-stabilized propargylic cation is reacted with a nucleophile. Oxidative demetallation gives the desired alkylated alkyne. [1] [2] It is named after Kenneth M. Nicholas. The Nicholas reaction. Several reviews have been published. [3] [4]
N is the number density of the molecules (number per cubic meter); α is the molecular polarizability in SI-units [C·m 2 /V]. In the case that the material consists of a mixture of two or more species, the right hand side of the above equation would consist of the sum of the molecular polarizability contribution from each species, indexed by i ...
The cubic-plus-chain (CPC) [28] [29] [30] equation of state hybridizes the classical cubic equation of state with the SAFT chain term. [21] [22] The addition of the chain term allows the model to be capable of capturing the physics of both short-chain and long-chain non-associating components ranging from alkanes to polymers. The CPC monomer ...
In the context of ocean currents, a volume of one million cubic meters may be imagined as a "slice" of ocean with dimensions 1 km × 1 km × 1 m (width × length × thickness). At this scale, these units can be more easily compared in terms of width of the current (several km), depth (hundreds of meters), and current speed (as meters per second ).
President Joe Biden pardoned five people on Sunday, including the late civil rights leader Marcus Garvey, and commuted the sentences of two, the White House said in a statement.. Garvey, who died ...
These plots were first introduced in a 1970 paper by R. A. More O’Ferrall to discuss mechanisms of β-eliminations [2] and later adopted by W. P. Jencks in an attempt to clarify the finer details involved in the general acid-base catalysis of reversible addition reactions to carbon electrophiles such as the hydration of carbonyls.
This year-long investigation provides an unprecedented look at California's one-party supermajority legislature through the eyes of grieving parents who discover how California lawmakers kill ...
The Dry January campaign was started in 2013 by Alcohol Change U.K., a charity focused on reducing alcohol harm. What are the health benefits of Dry January? While research on how quitting alcohol ...