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tert-Butyl chloride is the organochloride with the formula (CH 3) 3 CCl. It is a colorless, flammable liquid. It is sparingly soluble in water, with a tendency to undergo hydrolysis to the corresponding tert-butyl alcohol. It is produced industrially as a precursor to other organic compounds. [1]
The effect of the tert-butyl group on the progress of a chemical reaction is called the Thorpe–Ingold effect illustrated in the Diels-Alder reaction below. Compared to a hydrogen substituent, the tert-butyl substituent accelerates the reaction rate by a factor of 240. [2] tert-Butyl effect. The tert-butyl effect is an example of steric hindrance.
tert-Butyldimethylsilyl chloride is an organosilicon compound with the formula (Me 3 C)Me 2 SiCl (Me = CH 3). It is commonly abbreviated as TBSCl or TBDMSCl. It is a chlorosilane containing two methyl groups and a tert-butyl group. As such it is more bulky that trimethylsilyl chloride. It is a colorless or white solid that is soluble in many ...
tert-Butyl chloride (2-chloro-2-methylpropane) Index of chemical compounds with the same name This set index article lists chemical compounds articles associated with the same name.
n-Butyl chloride. Identifiers ... It can be prepared from 1-butanol by treatment with hydrogen chloride. [4] It reacts with lithium metal to give n-butyllithium: [5]
Tetrabutyltin is the organotin compound with the molecular formula Sn(CH 2 CH 2 CH 2 CH 3) 4 or SnBu 4, where Bu is butyl −CH 2 CH 2 CH 2 CH 3. Sometimes abbreviated TTBT, it is a colorless, lipophilic oil. [3] Tetrabutyltin is a precursor to tributyltin and dibutyltin compounds.
The tert-butyldiphenylsilyl group was first suggested as a protecting group by Hanessian and Lavallée in 1975. It was designed to supersede the use of Corey's tert-butyldimethylsilyl as a protecting group for alcohols:
General chemical structure of chloroformate esters. Chloroformates are a class of organic compounds with the formula ROC(O)Cl. They are formally esters of chloroformic acid. Most are colorless, volatile liquids that degrade in moist air. A simple example is methyl chloroformate, which is commercially available.