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A polycarbonate is an oxocarbon dianion consisting of a chain of carbonate units, where successive carbonyl groups are directly linked to each other by shared additional oxygen atoms. That is, they are the conjugate bases of polycarbonic acids , the conceptual anhydrides of carbonic acid , or polymers of carbon dioxide .
Polycarbonate is commonly used in eye protection, as well as in other projectile-resistant viewing and lighting applications that would normally indicate the use of glass, but require much higher impact-resistance. Polycarbonate lenses also protect the eye from UV light.
Values of range from below 25 for very dense flint glasses, around 34 for polycarbonate plastics, up to 65 for common crown glasses, and 75 to 85 for some fluorite and phosphate crown glasses. Most of the human eye's wavelength sensitivity curve, shown here, is bracketed by the Abbe number reference wavelengths of 486.1 nm (blue) and 656.3 nm (red)
Poisson's ratio of a material defines the ratio of transverse strain (x direction) to the axial strain (y direction)In materials science and solid mechanics, Poisson's ratio (symbol: ν ()) is a measure of the Poisson effect, the deformation (expansion or contraction) of a material in directions perpendicular to the specific direction of loading.
The Flory–Fox equation relates the number-average molecular weight, M n, to the glass transition temperature, T g, as shown below: =, where T g,∞ is the maximum glass transition temperature that can be achieved at a theoretical infinite molecular weight and K is an empirical parameter that is related to the free volume present in the polymer sample.
In this equation, k is the number of monomers in the chain, [1] and 0<a<1 is an empirically determined constant related to the fraction of unreacted monomer remaining. [ 2 ] The form of this distribution implies is that shorter polymers are favored over longer ones -the chain length is geometrically distributed .
The degree of polymerization, or DP, is the number of monomeric units in a macromolecule or polymer or oligomer molecule. [1] [2] [3]For a homopolymer, there is only one type of monomeric unit and the number-average degree of polymerization is given by ¯ ¯ = ¯, where ¯ is the number-average molecular weight and is the molecular weight of the monomer unit.
The conversion equations depend on the temperature at which the conversion is wanted (usually about 20 to 25 degrees Celsius). At an ambient air pressure of 1 atmosphere (101.325 kPa), the general equation is: = / ()
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