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The electric dipole moment is a measure of the separation of positive and negative electrical charges within a system: that is, a measure of the system's overall polarity. The SI unit for electric dipole moment is the coulomb-metre (C⋅m). The debye (D) is another unit of measurement used in atomic physics and chemistry.
The method of image charges (also known as the method of images and method of mirror charges) is a basic problem-solving tool in electrostatics.The name originates from the replacement of certain elements in the original layout with fictitious charges, which replicates the boundary conditions of the problem (see Dirichlet boundary conditions or Neumann boundary conditions).
The size of the induced dipole moment is equal to the product of the strength of the external field and the dipole polarizability of ρ. Dipole moment values can be obtained from measurement of the dielectric constant. Some typical gas phase values given with the unit debye are: [7] carbon dioxide: 0; carbon monoxide: 0.112 D; ozone: 0.53 D
Transition dipole moment, the electrical dipole moment in quantum mechanics; Molecular dipole moment, the electric dipole moment of a molecule. Bond dipole moment, the measure of polarity of a chemical bond; Electron electric dipole moment, the measure of the charge distribution within an electron; Magnetic dipole moment, the measure of the ...
Within the Standard Model, such a dipole is predicted to be non-zero but very small, at most 10 −38 e⋅cm, [2] where e stands for the elementary charge. The discovery of a substantially larger electron electric dipole moment would imply a violation of both parity invariance and time reversal invariance. [3] [4]
Note that the dipole moments drawn in this diagram represent the shift of the valence electrons as the origin of the charge, which is opposite the direction of the actual electric dipole moment. The bond dipole moment [5] uses the idea of electric dipole moment to measure the polarity of a chemical bond within a molecule. It occurs whenever ...
The moment of force, or torque, is a first moment: =, or, more generally, .; Similarly, angular momentum is the 1st moment of momentum: =.Momentum itself is not a moment.; The electric dipole moment is also a 1st moment: = for two opposite point charges or () for a distributed charge with charge density ().
The transition dipole moment is useful for determining if transitions are allowed under the electric dipole interaction. For example, the transition from a bonding π {\displaystyle \pi } orbital to an antibonding π ∗ {\displaystyle \pi ^{*}} orbital is allowed because the integral defining the transition dipole moment is nonzero.