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It is an example of an acid–base reaction with the monomeric oxyanion acting as a base and the condensed oxyanion acting as its conjugate acid. The reverse reaction is a hydrolysis reaction, as a water molecule, acting as a base, is split. Further condensation may occur, particularly with anions of higher charge, as occurs with adenosine ...
Phosphorus oxyanions (6 C, 5 P) S. Silicates (4 C, 41 P) Pages in category "Oxyanions" The following 39 pages are in this category, out of 39 total.
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Dissolution of oxides often gives oxyanions. Adding aqueous base to P 4 O 10 gives various phosphates. Adding aqueous base to MoO 3 gives polyoxometalates. Oxycations are rarer, some examples being nitrosonium (NO +), vanadyl (VO 2+), and uranyl (UO 2+ 2). Of course many compounds are known with both oxides and other groups.
For example, let us consider the carbonate(CO 2− 3) ion: H + + CO 2− 3 → HCO − 3, which is called either bicarbonate or hydrogen carbonate. The process that forms these ions is called protonation. Most of the common polyatomic anions are oxyanions, conjugate bases of oxyacids (acids derived from the oxides of non-metallic elements).
The number and identity of the oxyanions that exist between pH 13 and 2 depend on pH as well as concentration. For example, protonation of vanadate initiates a series of condensations to produce polyoxovanadate ions: [2] pH 9–12: HVO 2− 4, V 2 O 4− 7; pH 4–9: H 2 VO − 4, V 4 O 4− 12, HV 10 O 5− 28; pH 2–4: H 3 VO 4, H 2 V 10 O 4 ...
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The discrete molybdenum oxyanions range in size from the simplest MoO 2− 4, found in potassium molybdate up to extremely large structures found in isopoly-molybdenum blues that contain for example 154 Mo atoms. The behaviour of molybdenum is different from the other elements in group 6.