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An oxyanion, or oxoanion, is an ion with the generic formula A x O z− y (where A represents a chemical element and O represents an oxygen atom). Oxyanions are formed by a large majority of the chemical elements. [1] The formulae of simple oxyanions are determined by the octet rule. The corresponding oxyacid of an oxyanion is the compound H z ...
Ⓓ Rare earth metals are the group 3 metals scandium, yttrium, lutetium and the lanthanides; scandium is the only such metal shown as being capable of forming an oxyanion. Ⓔ Radioactive elements, such as the actinides, are harder to study. The known species may not represent the whole of what is possible, and the identifications may ...
Dissolution of oxides often gives oxyanions. Adding aqueous base to P 4 O 10 gives various phosphates. Adding aqueous base to MoO 3 gives polyoxometalates. Oxycations are rarer, some examples being nitrosonium (NO +), vanadyl (VO 2+), and uranyl (UO 2+ 2). Of course many compounds are known with both oxides and other groups.
The number and identity of the oxyanions that exist between pH 13 and 2 depend on pH as well as concentration. For example, protonation of vanadate initiates a series of condensations to produce polyoxovanadate ions: [2] pH 9–12: HVO 2− 4, V 2 O 4− 7; pH 4–9: H 2 VO − 4, V 4 O 4− 12, HV 10 O 5− 28; pH 2–4: H 3 VO 4, H 2 V 10 O 4 ...
Phosphorus oxyanions (6 C, 5 P) S. Silicates (4 C, 41 P) Pages in category "Oxyanions" The following 39 pages are in this category, out of 39 total.
In chemistry, a molybdate is a compound containing an oxyanion with molybdenum in its highest oxidation state of +6: O − −Mo(=O) 2 −O −. Molybdenum can form a very large range of such oxyanions, which can be discrete structures or polymeric extended structures, although the latter are only found in the solid state.
There are very few oxo-aqua ions of metals in the oxidation state +5 or higher. Rather, the species found in aqueous solution are monomeric and polymeric oxyanions. Oxyanions can be viewed as the end products of hydrolysis, in which there are no water molecules attached to the metal, only oxide ions.
The dithionite is the oxyanion with the formula [S 2 O 4] 2−. [1] It is commonly encountered as the salt sodium dithionite. For historical reasons, it is sometimes called hydrosulfite, but it contains no hydrogen and is not a sulfite. [2] The dianion has a steric number of 4 and trigonal pyramidal geometry.