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Rate equation. In chemistry, the rate equation (also known as the rate law or empirical differential rate equation) is an empirical differential mathematical expression for the reaction rate of a given reaction in terms of concentrations of chemical species and constant parameters (normally rate coefficients and partial orders of reaction) only ...
In physical chemistry, the Arrhenius equation is a formula for the temperature dependence of reaction rates.The equation was proposed by Svante Arrhenius in 1889, based on the work of Dutch chemist Jacobus Henricus van 't Hoff who had noted in 1884 that the van 't Hoff equation for the temperature dependence of equilibrium constants suggests such a formula for the rates of both forward and ...
A measure of disorder in the universe or of the unavailability of the energy in a system to do work. [7] Entropy and disorder also have associations with equilibrium. [8] Technically, entropy, from this perspective, is defined as a thermodynamic property which serves as a measure of how close a system is to equilibrium—that is, to perfect ...
In statistical physics, the kinetic theory of gases applies Newton's laws of motion to large numbers (typically on the order of the Avogadro number) of particles. Kinetic theory can explain, for example, the pressure that a gas exerts upon the container holding it as the aggregate of many impacts of atoms, each imparting a tiny amount of momentum.
Reaction (physics) As described by the third of Newton's laws of motion of classical mechanics, all forces occur in pairs such that if one object exerts a force on another object, then the second object exerts an equal and opposite reaction force on the first. [1][2] The third law is also more generally stated as: "To every action there is ...
Rate-determining step. In chemical kinetics, the overall rate of a reaction is often approximately determined by the slowest step, known as the rate-determining step (RDS or RD-step[1] or r/d step[2][3]) or rate-limiting step. For a given reaction mechanism, the prediction of the corresponding rate equation (for comparison with the experimental ...
Mass number. A = (Relative) atomic mass = Mass number = Sum of protons and neutrons. N = Number of neutrons. Z = Atomic number = Number of protons = Number of electrons. A = Z + N {\displaystyle A=Z+N\,\!} Mass in nuclei. M'nuc = Mass of nucleus, bound nucleons. MΣ = Sum of masses for isolated nucleons.
However, all reactions can be represented as a series of elementary reactions and, if the mechanism is known in detail, the rate equation for each individual step is given by the expression so that the overall rate equation can be derived from the individual steps. When this is done the equilibrium constant is obtained correctly from the rate ...