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Stoichiometry is often used to balance chemical equations (reaction stoichiometry). For example, the two diatomic gases, hydrogen and oxygen , can combine to form a liquid, water, in an exothermic reaction , as described by the following equation:
where A and B are reactants C is a product a, b, and c are stoichiometric coefficients,. the reaction rate is often found to have the form: = [] [] Here is the reaction rate constant that depends on temperature, and [A] and [B] are the molar concentrations of substances A and B in moles per unit volume of solution, assuming the reaction is taking place throughout the volume of the ...
The generalisation of the law of mass action, in terms of affinity, to equilibria of arbitrary stoichiometry was a bold and correct conjecture. The hypothesis that reaction rate is proportional to reactant concentrations is, strictly speaking, only true for elementary reactions (reactions with a single mechanistic step), but the empirical rate ...
In chemical thermodynamics, the reaction quotient (Q r or just Q) [1] is a dimensionless quantity that provides a measurement of the relative amounts of products and reactants present in a reaction mixture for a reaction with well-defined overall stoichiometry at a particular point in time.
The exponents, which can be fractional, [6] are called partial orders of reaction and their sum is the overall order of reaction. [7] In a dilute solution, an elementary reaction (one having a single step with a single transition state) is empirically found to obey the law of mass action. This predicts that the rate depends only on the ...
A solution of an equation is often called a root of the equation, particularly but not only for polynomial equations. The set of all solutions of an equation is its solution set. An equation may be solved either numerically or symbolically. Solving an equation numerically means that only numbers are admitted as solutions.
For reactions in aqueous solution, such as an acid dissociation reaction AH + H 2 O ⇌ A − + H 3 O + the concentration of water may be taken as being constant and the formation of the hydronium ion is implicit. AH ⇌ A − + H + Water concentration is omitted from expressions defining equilibrium constants, except when solutions are very ...
Considering finite changes instead of infinitesimal changes, one can write the equation for the extent of a reaction as = The extent of a reaction is generally defined as zero at the beginning of the reaction. Thus the change of is the extent itself. Assuming that the system has come to equilibrium,